{1'-Phenyl-1',2',5',6',7',7a'-hexahydro-spiro[indeno[1,2-b]quinoxaline-11,3'-pyrrolizin]-2'-yl}(p-tolyl)methanone

被引:3
|
作者
Srinivasan, T. [1 ]
Suhitha, S. [1 ]
Purushothaman, S. [2 ]
Raghunathan, R. [2 ]
Velmurugan, D. [1 ]
机构
[1] Univ Madras, Ctr Adv Study Crystallog & Biophys, Guindy Campus, Madras 600025, Tamil Nadu, India
[2] Univ Madras, Dept Organ Chem, Madras 600025, Tamil Nadu, India
关键词
D O I
10.1107/S1600536812031480
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C35H29N3O, the quinoxaline and indene systems are essentially planar, with maximum deviations of 0.047 (2) and 0.032 (2) angstrom for C atoms, respectively. The quinoxaline system forms a dihedral angle of 4.75 (3)degrees with the indene system. The pyrrolizine system is folded. The substituted five-membered ring adopts an envelope conformation. In the other five-membered ring, one C atom is disordered with a site-occupancy ratio of 0.676 (12): 0.324 (12). In the crystal, molecules are linked via C-H center dot center dot center dot O hydrogen bonds involving the bifurcated carbonyl O atom.
引用
收藏
页码:02469 / +
页数:12
相关论文
共 50 条
  • [31] 2′-(p-Methoxybenzoyl)-1′,2,2′,3,5′,6′,7′,7a′-octahydro-1H-indan-2-spiro-3′-(3′H-pyrrolizine)-1′-spiro-3"-1H-indoline-1,2",3-trione
    Seshadri, PR
    Selvanayagam, S
    Velmurugan, D
    Ravikumar, K
    Sureshbabu, AR
    Raghunathan, R
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1783 - O1785
  • [32] Crystal structures of 2 '-benzoyl-1 '-(4-methylphenyl)-1,1 ',2,2 ',5 ',6 ',7 ',7a '-octahydrospiro [indole3,3 '-pyrrolizin]-2-one and 2 '-(4-bromobenzoyl)-1 '(2-chlorophenyl)-1,1 ',2,2 ',5 ',6 ',7 ',7a '-octahydrospiro [indole-3,3 '-pyrrolizin]-2-one
    Chandrarekha, M.
    Srinivasan, N.
    Vijaya, P. Kottala
    Siva, A.
    Krishnakumar, R. V.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1637 - +
  • [33] 2,3,4,4A,5,9B-HEXAHYDRO-1H-INDENO[1,2-B]PYRIDINES - POTENTIAL ANTIDEPRESSANTS
    KUNSTMANN, R
    LERCH, U
    GERHARDS, H
    LEVEN, M
    SCHACHT, U
    JOURNAL OF MEDICINAL CHEMISTRY, 1984, 27 (04) : 432 - 439
  • [34] (6,6-Dimethyl-1-phenyl-6,7-dihydro-5H-pyrrolizin-2-yl)(thiophen-2-yl)methanone
    Liu, Yu-Min
    Zhong, Jia-Liang
    Sun, Wen-Xia
    Zhang, Fu-Li
    Liu, He
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1513 - +
  • [35] 7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2"-indan]-1,3,1"-trione
    Wei, Ang Chee
    Ali, Mohamed Ashraf
    Choon, Tan Soo
    Quah, Ching Kheng
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3218 - U1944
  • [36] 3-(4-methyl-1,3-thiazol-5-yl)-1-[1′-(4-methyl-1,3-thiazol-5-yl)-2-oxo-2,3,2′,3′,5′,6′,7′,7a′-octahydro-1H-indole-3-spiro-3′-1H-pyrrolizin-2′-yl]prop-2-en-1-one
    Ramesh, P.
    Murugavel, S.
    SubbiahPandi, A.
    Murugan, R.
    Narayanan, S. Sriman
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4106 - U3577
  • [37] 2′-(2-Chlorophenyl)-1′-nitro-2′,3′,4′,5′,6′,7′-hexahydro-1H-indole-3-spiro-3′-1′H-pyrrolizin-2(3H)-one
    Usha, G
    Selvanayagam, S
    Velmurugan, D
    Ravikumar, K
    Raghunathan, R
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O3299 - O3301
  • [38] 6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo-[1,2-c][1,3]thiazole-5,11'-indeno-[1,2-b]quinoxaline]
    Suhitha, Sivasubramanian
    Gunasekaran, Krishnaswamy
    Sureshbabu, Adukamparai Rajukrishnan
    Raghunathan, Raghavachary
    Velmurugan, Devadasan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M500 - +
  • [39] Synthesis of Dispiro[indeno[1,2-b]quinoxaline-11,1′-pyrrolo-[2,1-a]isoquinoline-3′,3′′-indolin]-2′′-one Derivatives via Cycloaddition Reactions
    Yan, Jin-Long
    Wu, Ya-Wen
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (SUPPL 1) : S131 - S136
  • [40] 2,3,4,4A,9,9A-HEXAHYDRO-9-PHENYL-1H-INDENO[1,2-B]PYRAZINES - POTENTIAL ANTIDEPRESSANTS
    CHAHBOUN, S
    GELBCKE, M
    SMITH, DF
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1995, 104 (10): : 613 - 622