{1'-Phenyl-1',2',5',6',7',7a'-hexahydro-spiro[indeno[1,2-b]quinoxaline-11,3'-pyrrolizin]-2'-yl}(p-tolyl)methanone

被引:3
|
作者
Srinivasan, T. [1 ]
Suhitha, S. [1 ]
Purushothaman, S. [2 ]
Raghunathan, R. [2 ]
Velmurugan, D. [1 ]
机构
[1] Univ Madras, Ctr Adv Study Crystallog & Biophys, Guindy Campus, Madras 600025, Tamil Nadu, India
[2] Univ Madras, Dept Organ Chem, Madras 600025, Tamil Nadu, India
关键词
D O I
10.1107/S1600536812031480
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C35H29N3O, the quinoxaline and indene systems are essentially planar, with maximum deviations of 0.047 (2) and 0.032 (2) angstrom for C atoms, respectively. The quinoxaline system forms a dihedral angle of 4.75 (3)degrees with the indene system. The pyrrolizine system is folded. The substituted five-membered ring adopts an envelope conformation. In the other five-membered ring, one C atom is disordered with a site-occupancy ratio of 0.676 (12): 0.324 (12). In the crystal, molecules are linked via C-H center dot center dot center dot O hydrogen bonds involving the bifurcated carbonyl O atom.
引用
收藏
页码:02469 / +
页数:12
相关论文
共 50 条
  • [21] 6-Ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole5,11'-indeno[1,2-b]quinoxaline]
    Suhitha, Sivasubramanian
    Gunasekaran, Krishnaswamy
    Gavaskar, Deivasigamani
    Raghunathan, Raghavachary
    Velmurugan, Devadasan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M501 - +
  • [22] [6-(Furan-2-yl)-7-nitro-2,3,4,6,7,8-hexahydro- 1H-pyrido[1,2-a] pyrimidin-9-yl]( phenyl) methanone
    Zhang, Wen-Feng
    Xia, Jian-Hui
    Xu, Zhao-Hui
    Wang, Li-Ben
    Yu, Chu-Yi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O986 - +
  • [23] 1 ',1 ''-Dimethyl-4 '-phenyldispiro[11H-indeno[1,2-b]quinoxaline-11,2 '-pyrrolidine-3 ',3 ''-piperidin]-4 ''-one
    Suresh, J.
    Nagalakshmi, R. A.
    Malathi, K.
    Kumar, R. R.
    Lakshman, P. L. N.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1433 - +
  • [25] 2′-Methyl-2′-nitro-1′-phenyl-2′,3′,5′,6′,7′,7a′-hexahydrospiro[indoline-3,3′-1′H-pyrrolizin]-2-one
    Sarrafi, Yaghoub
    Alimohammadi, Kamal
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1490 - U2281
  • [26] (Naphthalen-1-yl){2-[(5,6,7,8-tetrahydronaphthalen-2-yl)-carbonyl] phenyl}methanone
    Kanchanadevi, J.
    Anbalagan, G.
    Sivasakthikumaran, R.
    Mohanakrishnan, A. K.
    Gunasekaran, B.
    Manivannan, V.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1201 - +
  • [27] 6a-Nitro-6-(2,2,7,7-tetramethyltetrahydro-3aH-bis[1,3]dioxolo[4,5-b:4 ',5 '-d]-pyran-5-yl)-6a,6b,7,8,9,11a-hexahydro6H-spiro[chromeno[3,4-a]pyrrolizine-11,11 '-indeno[1,2-b]quinoxaline]
    Anuradha, T.
    Rao, J. Naga Siva
    Seshadri, P. R.
    Raghunathan, R.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O38 - +
  • [28] 2-Phenyl-5-(p-tolyl)-1,3,4-oxadiazole
    Cordes, David B.
    Hua, Guoxiong
    Slawin, Alexandra M. Z.
    Woollins, J. Derek
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1757 - U1290
  • [29] Synthesis, Characterization and Antimicrobial Evaluation of Novel 6′-Amino-spiro[indeno[1,2-b]quinoxaline [1,3]dithiine]-5′-carbonitrile Derivatives
    Moghaddam-Manesh, Mohammadreza
    Ghazanfari, Dadkhoda
    Sheikhhosseini, Enayatollah
    Akhgar, Mohammadreza
    ACTA CHIMICA SLOVENICA, 2020, 67 (01) : 276 - 282
  • [30] Crystal structure of methyl 3 '-benzamido-4 '-(4-methoxyphenyl)-1 '-methylspiro[indeno[1,2-b]quinoxaline-11,2 '-pyrrolidine]-3 '-carboxylate
    Chandralekha, Kuppan
    Sureshbabu, Adukamparai Rajukrishnan
    Gavaskar, Deivasigamani
    Lakshmi, Srinivasakannan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1257 - +