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A NOVEL TYPE OF PHOTOSUBSTITUTION OF [FAC-RE(BPY)(CO)3BR] (BPY = 2,2'-BIPYRIDINE) WITH P(OR)3 IN THE PRESENCE OF TRIETHYLAMINE - EFFICIENT FORMATION OF [RE(BPY)(CO)2[P(OR)3]2]+BR-
被引:12
|作者:
PAC, CJ
KASEDA, S
ISHII, K
YANAGIDA, S
机构:
关键词:
D O I:
10.1039/c39910000787
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Photochemical ligand substitution of [fac-Re(bpy)(CO)3Br] with P(OEt)3 in the presence of triethylamine quantitatively gave [Re(bpy)(CO)2{P(OEt)3}3]+Br- without the intervention of a mono-substituted product.
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页码:787 / 788
页数:2
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