A NOVEL TYPE OF PHOTOSUBSTITUTION OF [FAC-RE(BPY)(CO)3BR] (BPY = 2,2'-BIPYRIDINE) WITH P(OR)3 IN THE PRESENCE OF TRIETHYLAMINE - EFFICIENT FORMATION OF [RE(BPY)(CO)2[P(OR)3]2]+BR-

被引：12

作者：

PAC, CJ

KASEDA, S

ISHII, K

YANAGIDA, S

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 11期

关键词：

D O I：

10.1039/c39910000787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photochemical ligand substitution of [fac-Re(bpy)(CO)3Br] with P(OEt)3 in the presence of triethylamine quantitatively gave [Re(bpy)(CO)2{P(OEt)3}3]+Br- without the intervention of a mono-substituted product.

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页码：787 / 788

页数：2

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