Photocatalytic reduction of acetylpyridine to pinacol using [fac-Re(bpy)(CO)3{4-(MeCO)py}]+ (bpy = 2,2′-bipyridine, py = pyridine)

被引：4

作者：

Hori, H

Koike, K

Takeuchi, K

Ishitani, O

机构：

[1] Natl Inst Resources & Environm, Tsukuba, Ibaraki 3058569, Japan

[2] Saitama Univ, Grad Sch Sci & Engn, Urawa, Saitama 3388570, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 04期

关键词：

D O I：

10.1246/cl.2000.376

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[fac-Re(bpy)(CO)(3){4(MeCO)py}](+) can act as an efficient photocatalyst for the reduction of 4-acetylpyridine to a pinacol (py-CMeOHCMeOH-py) in the presence of triethanolamine. The reaction proceeds via formation of a pinacol complex [fac-Re(bpy)(Co)(3)(py-CMeOHCMeOH-py)](+).

引用

页码：376 / 377

页数：2

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