KINETICS AND MECHANISM OF OXIDATION OF CYCLANOLS BY BIPYRIDINIUM CHLOROCHROMATE IN ACID-MEDIUM

被引：0
|
作者：
KABILAN, S
VETRICHELVAN, K
SANKAR, P
KRISHNASAMY, K
机构：
来源：
AFINIDAD | 1994年 / 51卷 / 450期
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D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Kinetics of oxidation of cyclopentanol, cyclohexanol, cycloheptanol and cyclooctanol by Bipyridinium chlorochromate (BPCC) in the presence of H+ ions are reported. The order in [BPCC], [cyclanol] and [H+] is one each. The relative reactivity of cyclanols viz. Cyclohexanol < cyclopentanol < cycloheptanol < cyclooctanol, has been explained on the basis of I-strain theory.
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页码：169 / 172
页数：4
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