KINETICS AND MECHANISM OF OXIDATION OF CYCLANOLS BY BIPYRIDINIUM CHLOROCHROMATE IN ACID-MEDIUM

被引：0
|
作者：
KABILAN, S
VETRICHELVAN, K
SANKAR, P
KRISHNASAMY, K
机构：
来源：
AFINIDAD | 1994年 / 51卷 / 450期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Kinetics of oxidation of cyclopentanol, cyclohexanol, cycloheptanol and cyclooctanol by Bipyridinium chlorochromate (BPCC) in the presence of H+ ions are reported. The order in [BPCC], [cyclanol] and [H+] is one each. The relative reactivity of cyclanols viz. Cyclohexanol < cyclopentanol < cycloheptanol < cyclooctanol, has been explained on the basis of I-strain theory.
引用
收藏
页码：169 / 172
页数：4
相关论文
共 50 条
  • [1] KINETICS AND MECHANISM OF SULFITE OXIDATION BY PERMANGANATE IN ACID-MEDIUM
    ERNST, T
    CYFERT, M
    [J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-LEIPZIG, 1987, 268 (01): : 175 - 180
  • [2] Kinetics and mechanism of the oxidation of diols by 2,2'-bipyridinium chlorochromate
    Loonker, K
    Sharma, PK
    Banerji, KK
    [J]. JOURNAL OF CHEMICAL RESEARCH-S, 1997, (07): : 242 - &
  • [3] KINETICS AND MECHANISM OF OXIDATION OF ACETANILIDE BY QUINQUEVALENT VANADIUM IN ACID-MEDIUM
    GUPTA, R
    [J]. MONATSHEFTE FUR CHEMIE, 1990, 121 (8-9): : 571 - 576
  • [4] Kinetics and mechanism of the oxidation of organic sulphides by 2,2′-bipyridinium chlorochromate
    Vyas, Shashi
    Sharma, Pradeep K.
    [J]. 2002, Indian Academy of Sciences (114):
  • [5] Kinetics and mechanism of oxidation of secondary alcohols by 2,2′-bipyridinium chlorochromate
    Vyas, S
    Sharma, PK
    [J]. OXIDATION COMMUNICATIONS, 2001, 24 (02): : 248 - 256
  • [6] Kinetics and mechanism of oxidation of aliphatic aldehydes by 2,2′-bipyridinium chlorochromate
    Kumbhat, V
    Sharma, PK
    Banerji, KK
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2000, 39 (11): : 1169 - 1173
  • [7] KINETICS AND MECHANISM OF THE OXIDATION OF SOME THIOACIDS BY 2,2'-BIPYRIDINIUM CHLOROCHROMATE
    RATHORE, S
    SHARMA, PK
    BANERJI, KK
    [J]. JOURNAL OF CHEMICAL RESEARCH-S, 1994, (08): : 298 - 299
  • [8] Kinetics and mechanism of oxidation of cyclanols by pyridinium dichromate in acetonitrile medium
    Girija, R
    Kabilan, S
    [J]. OXIDATION COMMUNICATIONS, 1999, 22 (03): : 395 - 399
  • [9] Kinetics and mechanism of the oxidation of organic sulphides by 2,2′-bipyridinium chlorochromate
    Vyas S.
    Sharma P.K.
    [J]. Proceedings of the Indian Academy of Sciences: Chemical Sciences, 2002, 114 (02) : 137 - 148
  • [10] KINETICS AND MECHANISM OF OXIDATION OF SOME ALIPHATIC ESTERS BY BROMATE IN ACID-MEDIUM
    CHAR, PN
    SONDU, S
    SETHURAM, B
    RAO, TN
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1989, 28 (08): : 670 - 672
12345