Diaquabis(nicotinamide-kappa N-1) bis(thiocyanato-kappa S) cobalt(II)

被引：2
|
作者：
Pandey, Deepanjali [1 ]
Narvi, Shahid S. [1 ]
Chaudhuri, Siddhartha [2 ]
机构：
[1] Motilal Nehru Natl Inst Technol, Dept Chem, Allahabad 211004, Uttar Pradesh, India
[2] Bose Inst, Kolkata 700009, W Bengal, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
D O I：
10.1107/S1600536814011453
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Co(NCS)(2)(C6H6N2O)(2)(H2O)(2)], the Co-II cation is located on an inversion centre and is coordinated by two thiocyanate anions, two nicotinamide molecules and two water molecules in a distorted N2O2S2 octahedral geometry. The amide group is twisted by 31.30 (16)degrees with respect to the pyridine ring. In the crystal, molecules are linked by O-H center dot center dot center dot O, O-H center dot center dot center dot S and N-H center dot center dot center dot S hydrogen bonds into a three-dimensional supramolecular network. Weak pi-pi stacking is observed between parallel pyridine rings of adjacent molecules, the centroid-centroid distance being 3.8270 (19) angstrom.
引用
收藏
页码：M236 / +
页数：8
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