THE CATALYTIC-OXIDATION OF METHANOL IN OSCILLATORY REGIME

被引：0
|
作者：
IONESCU, NI
CHIRCA, MS
MARCHIDAN, DI
机构：
来源：
REVUE ROUMAINE DE CHIMIE | 1991年 / 36卷 / 4-7期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Methanol oxidation on a palladium catalyst may proceed in oscillatory regime if an adequate correlation among various factors - reaction cell temperature, methanol content, oxygen flow rate, catalyst sample weight and its disposal on the metallic support - is realized. The influence of these factors upon the appearance and the characteristics of the thermal oscillations is presented. An attempt is made to propose a possible mechanism for the oscillatory behaviour, based on the reactivity of the intermediate PdxO phase.
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页码：809 / 818
页数：10
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