TRIS(4-TERT-BUTYLPHENYL)CHLOROTIN(IV)

被引:9
|
作者
WHARF, I
SIMARD, MG
MCGINN, K
机构
[1] UNIV MONTREAL,DEPT CHIM,MONTREAL,PQ H3C 3J7,CANADA
[2] MCGILL UNIV,DEPT CHEM,MONTREAL,PQ H3A 2K6,CANADA
关键词
D O I
10.1107/S010827019400987X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of tris(4-tert-butylphenyl)chlorotin(IV), [Sn(C10H13)3Cl], has been determined by single-crystal X-ray diffraction. It crystallizes in a space group (C2/c) which differs from those usually found for triaryltin halides. The structure comprises molecules forming ladders using overlapping aryl or tert-butyl groups. This relatively open but organized arrangement contrasts with the more closely packed but random one found for Ph3SnCl and may account for the differences in physical properties of these two triaryltin chlorides.
引用
收藏
页码:236 / 238
页数:3
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