Racemic 4-(4-tert-butylphenyl)-2,6-dimethylcyclohex-3-enecarboxylic acid

被引:3
|
作者
Xie, Songwen [2 ]
O'Hearn, Caryn R. [2 ]
Robinson, Paul D. [1 ]
机构
[1] So Illinois Univ, Dept Geol, Carbondale, IL 62901 USA
[2] Indiana Univ, Dept Nat Informat & Math Sci, Kokomo, IN 46904 USA
基金
美国国家科学基金会;
关键词
D O I
10.1107/S1600536808003309
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The chirality of the title compound, C19H26O2, is solely generated by the presence of the double bond in the cyclohexene ring. This compound was synthesized to study the interaction of the two enantiomers in the solid state. The resultant racemate is made up of carboxylic acid RS dimers. Intermolecular O-H center dot center dot center dot O hydrogen bonds produce centro-symmetric R-2(2)(8) rings which dimerize the two chiral enantiomers through their carboxyl groups.
引用
收藏
页码:O554 / U803
页数:10
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