KINETIC FEATURES OF LOW-TEMPERATURE CATALYTIC CONVERSION OF STRAIGHT-RUN GASOLINE ON Co-HZSM-SO42-/ZrO2

被引：0

作者：

Abasov, Safa, I ^{[1
]}

Aghayeva, Suraya B. ^{[1
]}

Alimardanov, Hafiz M. ^{[1
]}

Taghiyev, Dilgam B. ^{[1
]}

Veliyeva, Firuza M. ^{[1
]}

Mammadova, Malahat T. ^{[1
]}

Iskenderova, Aytan A. ^{[1
]}

Imanova, Arzu A. ^{[1
]}

Isayeva, Yegana S. ^{[1
]}

机构：

[1] Azerbaijan Natl Acad Sci, YH Mammadaliyev Inst Petrochem Proc, 30 Khojaly Ave, AZ-1025 Baku, Azerbaijan

来源：

PROCESSES OF PETROCHEMISTRY AND OIL REFINING | 2018年 / 19卷 / 02期

关键词：

straight-run gasoline; isomerization; disproportionation; kinetic regularities; HZSM; izo-C-5-C-6;

D O I：

暂无

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Kinetic regularities of the involvement of C7+ components of straight-run gasoline in the conjugated isomerization and disproportionation process for obtaining of high-octane isomeric components of C-5-C-6 on the composite Co-HZSM-SO42-/ZrO2 catalyst are established. A regression model of the process is created, activation energies are calculated. It was found that the limiting stage of the PSRG transformation is the primary isomerization of the C7+ components, proceeds more fovarabbly, which is facilitated by low activation energies. Proposed that the resulting model will be used to make the mechanism of the course of the main and adverse reactions

引用

页码：191 / 197

页数：7

共 50 条

[31] Enhanced low-temperature CO2 methanation performance of Ni/ZrO2 catalysts via a phase engineering strategy
Ma, Lixuan
Ye, Runping
Huang, Yuanyuan
Reina, Tomas Ramirez
Wang, Xinyao
Li, Congming
Zhang, Xiao Li
Fan, Maohong
Zhang, Riguang
Liu, Jian
Chemical Engineering Journal, 2022, 446
[32] Enhanced low-temperature CO2 methanation performance of Ni/ZrO2 catalysts via a phase engineering strategy
Ma, Lixuan
Ye, Runping
Huang, Yuanyuan
Reina, Tomas Ramirez
Wang, Xinyao
Li, Congming
Zhang, Xiao Li
Fan, Maohong
Zhang, Riguang
Liu, Jian
CHEMICAL ENGINEERING JOURNAL, 2022, 446
[33] Influence of zirconia crystal phase on the catalytic performance of Au/ZrO2 catalysts for low-temperature water gas shift reaction
Li, Juan
Chen, Junli
Song, Wei
Liu, Junlong
Shen, Wenjie
APPLIED CATALYSIS A-GENERAL, 2008, 334 (1-2) : 321 - 329
[34] Low-temperature complete combustion of methane over Mn-, Co-, and Fe-stabilized ZrO2
Choudhary, VR
Uphade, BS
Pataskar, SG
Keshavaraja, A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (20) : 2393 - 2395
[35] Preparation and characterization of sulfated zirconia(SO42-/ZrO2)/Nafion composite membranes for PEMFC operation at high temperature/low humidity
Zhai, Yunfeng
Zhang, Huamin
Hu, Jingwei
Yi, Baolian
JOURNAL OF MEMBRANE SCIENCE, 2006, 280 (1-2) : 148 - 155
[36] Mn-Co binary oxides for low-temperature catalytic oxidation of NO: effect of SO2 and regeneration
Tang, Xiaolong
Chen, Du
Chu, Chao
Gao, Fengyu
Yi, Honghong
Wang, Chengzhi
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2021, 96 (10) : 2956 - 2964
[37] Catalytic methanation performance in a low-temperature slurry-bed reactor over Ni–ZrO2 catalyst: effect of the preparation method
Fanhui Meng
Yan Song
Xin Li
Yang Cheng
Zhong Li
Journal of Sol-Gel Science and Technology, 2016, 80 : 759 - 768
[38] Greener production of styrene via low-temperature dehydration of phenethyl alcohol over Co-supported P/ZrO2
Dhiman, Neha
Joshi, Bhanu
Yenumala, Sudhakara Reddy
Singh, Omvir
Bal, Rajaram
Ray, Anjan
Sarkar, Bipul
CHEMICAL ENGINEERING JOURNAL, 2024, 480
[39] Study on catalytic properties and stability of SO42-/ZrO2-TiO2 solid superacid prepared by ageing method at low temperature
Chen, TY
Gu, XP
Hu, XY
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2002, 18 (04) : 378 - 382
[40] Chemical conversion of SO2 in low-temperature and low-pressure oxyhydrogen flames. 1. Kinetic analysis of the process
A. A. Mantashyan
E. M. Makaryan
A. A. Arutyunyan
G. M. Gevorgyan
Combustion, Explosion, and Shock Waves, 2016, 52 : 643 - 650

← 1 2 3 4 5 →