KINETIC FEATURES OF LOW-TEMPERATURE CATALYTIC CONVERSION OF STRAIGHT-RUN GASOLINE ON Co-HZSM-SO42-/ZrO2

被引：0
|
作者：
Abasov, Safa, I [1 ]
Aghayeva, Suraya B. [1 ]
Alimardanov, Hafiz M. [1 ]
Taghiyev, Dilgam B. [1 ]
Veliyeva, Firuza M. [1 ]
Mammadova, Malahat T. [1 ]
Iskenderova, Aytan A. [1 ]
Imanova, Arzu A. [1 ]
Isayeva, Yegana S. [1 ]
机构：
[1] Azerbaijan Natl Acad Sci, YH Mammadaliyev Inst Petrochem Proc, 30 Khojaly Ave, AZ-1025 Baku, Azerbaijan
来源：
PROCESSES OF PETROCHEMISTRY AND OIL REFINING | 2018年 / 19卷 / 02期
关键词：
straight-run gasoline; isomerization; disproportionation; kinetic regularities; HZSM; izo-C-5-C-6;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Kinetic regularities of the involvement of C7+ components of straight-run gasoline in the conjugated isomerization and disproportionation process for obtaining of high-octane isomeric components of C-5-C-6 on the composite Co-HZSM-SO42-/ZrO2 catalyst are established. A regression model of the process is created, activation energies are calculated. It was found that the limiting stage of the PSRG transformation is the primary isomerization of the C7+ components, proceeds more fovarabbly, which is facilitated by low activation energies. Proposed that the resulting model will be used to make the mechanism of the course of the main and adverse reactions
引用
收藏
页码：191 / 197
页数：7
相关论文
共 50 条
  • [21] Charaterization and catalytic activity of CuO and NiO supported on ZrO2 for CO low temperature oxidation
    Chen Zhi
    Xie Yi-Long
    Qiu Jin-Xing
    Chen Zhong-He
    MATERIALS, MECHANICAL AND MANUFACTURING ENGINEERING, 2014, 842 : 237 - 241
  • [22] Co-doped MnCeOx/ZrO2 catalysts for low temperature selective catalytic reduction of NO
    Wang, Guangying
    Liang, Yan
    Song, Jian
    Xu, Kui
    Pan, Youchun
    Xu, Xiaolong
    Zhao, Yu
    RESEARCH ON CHEMICAL INTERMEDIATES, 2022, 48 (06) : 2627 - 2640
  • [23] Co-doped MnCeOx/ZrO2 catalysts for low temperature selective catalytic reduction of NO
    Guangying Wang
    Yan Liang
    Jian Song
    Kui Xu
    Youchun Pan
    Xiaolong Xu
    Yu Zhao
    Research on Chemical Intermediates, 2022, 48 : 2627 - 2640
  • [24] Mesoporous CuO/ZrO2 nanocatalysts: synthesis, characterization and low-temperature CO oxidation activities
    Jianliang Cao
    Yan Wang
    Jianchao Shi
    Guang Sun
    Zhanying Zhang
    Journal of Porous Materials, 2011, 18 : 667 - 672
  • [25] Mesoporous CuO/ZrO2 nanocatalysts: synthesis, characterization and low-temperature CO oxidation activities
    Cao, Jianliang
    Wang, Yan
    Shi, Jianchao
    Sun, Guang
    Zhang, Zhanying
    JOURNAL OF POROUS MATERIALS, 2011, 18 (06) : 667 - 672
  • [26] Comparative study of Au/TiO2 and Au/ZrO2 catalysts for low-temperature CO oxidation
    Grunwaldt, JD
    Maciejewski, M
    Becker, OS
    Fabrizioli, P
    Baiker, A
    JOURNAL OF CATALYSIS, 1999, 186 (02) : 458 - 469
  • [27] THE ROLE OF ZIRCONIUM DIOXIDE IN THE ACTIVATION OF WATER AND AS THE CATALYTIC SITE FOR LOW-TEMPERATURE STEAM REFORMING OVER RH/ZRO2
    IGARASHI, A
    OHTAKA, T
    HONNMA, T
    FUKUHARA, C
    STUDIES IN SURFACE SCIENCE AND CATALYSIS, 1993, 75 : 2083 - 2086
  • [28] Effect of SO2 on the low-temperature selective catalytic reduction of nitric oxide with ammonia over TiO2, ZrO2, and Al2O3
    Notoya, F
    Su, CL
    Sasaoka, E
    Nojima, S
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (17) : 3732 - 3739
  • [29] Catalytic performance and mechanism of SO42-/ZrO2/SBA-15 catalyst for CO2 desorption in CO2-loaded monoethanolamine solution
    Gao, Hongxia
    Huang, Yufei
    Zhang, Xiaowen
    Bairq, Zain Ali Saleh
    Huang, Yangqiang
    Tontiwachwuthikul, Paitoon
    Liang, Zhiwu
    APPLIED ENERGY, 2020, 259 (259)
  • [30] Low-temperature CO oxidation over Cu/Pt co-doped ZrO2 nanoparticles synthesized by solution combustion
    Singhania, Amit
    Gupta, Shipra Mital
    BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2017, 8 : 1546 - 1552
12345