KINETIC FEATURES OF LOW-TEMPERATURE CATALYTIC CONVERSION OF STRAIGHT-RUN GASOLINE ON Co-HZSM-SO42-/ZrO2

被引：0
|
作者：
Abasov, Safa, I [1 ]
Aghayeva, Suraya B. [1 ]
Alimardanov, Hafiz M. [1 ]
Taghiyev, Dilgam B. [1 ]
Veliyeva, Firuza M. [1 ]
Mammadova, Malahat T. [1 ]
Iskenderova, Aytan A. [1 ]
Imanova, Arzu A. [1 ]
Isayeva, Yegana S. [1 ]
机构：
[1] Azerbaijan Natl Acad Sci, YH Mammadaliyev Inst Petrochem Proc, 30 Khojaly Ave, AZ-1025 Baku, Azerbaijan
来源：
PROCESSES OF PETROCHEMISTRY AND OIL REFINING | 2018年 / 19卷 / 02期
关键词：
straight-run gasoline; isomerization; disproportionation; kinetic regularities; HZSM; izo-C-5-C-6;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Kinetic regularities of the involvement of C7+ components of straight-run gasoline in the conjugated isomerization and disproportionation process for obtaining of high-octane isomeric components of C-5-C-6 on the composite Co-HZSM-SO42-/ZrO2 catalyst are established. A regression model of the process is created, activation energies are calculated. It was found that the limiting stage of the PSRG transformation is the primary isomerization of the C7+ components, proceeds more fovarabbly, which is facilitated by low activation energies. Proposed that the resulting model will be used to make the mechanism of the course of the main and adverse reactions
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页码：191 / 197
页数：7
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