A RARE EXAMPLE OF 3 C-H ACTIVATIONS OF THE METHYL-GROUP - SYNTHESIS AND CRYSTAL-STRUCTURE OF [FE3(CO)9(MU-3-C=N(CH3)2)(MU-3-CC2H5)]

被引：8

作者：

JEANNIN, S ^{[1
]}

JEANNIN, Y ^{[1
]}

ROBERT, F ^{[1
]}

ROSENBERGER, C ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM METAUX TRANSIT LAB,CNRS,URA 419,4 PL JUSSIEU,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 448卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80079-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A di-mu3-carbyne cluster [Fe3(CO)9{mu3-C=N(CH3)2)(mu3-CC2H5)] has been synthesized by reaction of [Fe2(CO)9] with the alkynylethyl sulphide C2H5SC=CCH3 and trimethylamine oxide at 69-degrees-C. One of the mu3-carbyne functions resulted from the rare activation of the three C-H bonds of a trimethylamine methyl group.

引用

页码：151 / 155

页数：5

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