A RARE EXAMPLE OF 3 C-H ACTIVATIONS OF THE METHYL-GROUP - SYNTHESIS AND CRYSTAL-STRUCTURE OF [FE3(CO)9(MU-3-C=N(CH3)2)(MU-3-CC2H5)]

被引：8

作者：

JEANNIN, S ^{[1
]}

JEANNIN, Y ^{[1
]}

ROBERT, F ^{[1
]}

ROSENBERGER, C ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM METAUX TRANSIT LAB,CNRS,URA 419,4 PL JUSSIEU,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 448卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80079-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A di-mu3-carbyne cluster [Fe3(CO)9{mu3-C=N(CH3)2)(mu3-CC2H5)] has been synthesized by reaction of [Fe2(CO)9] with the alkynylethyl sulphide C2H5SC=CCH3 and trimethylamine oxide at 69-degrees-C. One of the mu3-carbyne functions resulted from the rare activation of the three C-H bonds of a trimethylamine methyl group.

引用

页码：151 / 155

页数：5

共 50 条

[31] PREPARATION AND CRYSTAL STRUCTURE OF (CH3)5AL2N(C6H5)2 MU-DIPHENYLAMINO-MU-METHYL-TETRAMETHYLDIALUMINUM
MAGNUSON, VR
STUCKY, GD
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (12) : 3269 - &
[32] ALKYLATION OF SALTS OF THE TRIOSMIUM ANIONS [OS3(EQ-ETA-1-C(O)CH3)(CO)11]-, [OS3(MU-O=C(CH3))(CO)10]-, AND [OS3(C(O)R)(MU-H-MU-O=C(CH3))(CO)9]-, R = CH3 OR C6H5 - CRYSTAL AND MOLECULAR-STRUCTURE OF OS3(1-ETA-1-C(OCH3)CH3)(1,2-MU-H-1,2-MU-O=C(CH3))(CO)9
JENSEN, CM
KNOBLER, CB
KAESZ, HD
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (20) : 5926 - 5933
[33] FORMYL AND ACYL DERIVATIVES OF FE3(MU-3-NPH)2(CO)9 - CRYSTAL AND MOLECULAR-STRUCTURE OF FE3(MU-3-NPH)2(CO)8(C(OET)PH)
WILLIAMS, GD
WHITTLE, RR
GEOFFROY, GL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 188 (AUG): : 179 - INOR
[34] REACTIVITY OF THE LINEAR TETRANUCLEAR RUTHENIUM CLUSTER RU4(CO)10[CH3C=C(H)C(H)=NC(H)(CH3)2]2 TOWARD CO - REGIOSELECTIVE ALIPHATIC C-H ACTIVATION PROCESSES AND THE X-RAY CRYSTAL-STRUCTURE OF RU2(CO)6[CH3CC(H)C(H)N=C(CH3)2]1
MUL, WP
ELSEVIER, CJ
VRIEZE, K
ORGANOMETALLICS, 1992, 11 (05) : 1891 - 1901
[35] Metal substitution reaction in the cluster (mu-H)(2)Fe-3(mu(3)-Se)(CO)(9) .4. Crystal and molecular structure of [Fe2W2(mu(3)-Se)(2)(mu(3)-CO)(mu-CO)(CO)(5)(eta(5)-C5H5)(2)]
Konchenko, SN
Virovets, AV
Podberezskaya, NV
POLYHEDRON, 1997, 16 (10) : 1689 - 1691
[36] STRUCTURAL STUDIES ON RUTHENIUM CARBONYL HYDRIDES .13. SYNTHESIS OF (MU-H)3RU3(MU-3-CSET)(CO)9 AND ITS REARRANGEMENT TO (MU-H)RU3(MU-3-ETA-2-CH2SET)(CO)9 - CRYSTAL-STRUCTURE OF (MU-H)RU3(MU-3-ETA-2-CH2SET)(CO)9
CHURCHILL, MR
ZILLER, JW
DALTON, DM
KEISTER, JB
ORGANOMETALLICS, 1987, 6 (04) : 806 - 812
[37] SYNTHESIS OF [ASPH4][FE3(CO)9(MU-CO)(MU(3)-HBCL)] BY OXIDATIVE CHLORIDE SUBSTITUTION OF [FE3(CO)9(MU(3)-HBCO)]2
CRASCALL, LE
THIMMAPPA, BHS
RHEINGOLD, AL
OSTRANDER, R
FEHLNER, TP
ORGANOMETALLICS, 1994, 13 (06) : 2153 - 2158
[38] STRUCTURAL CHEMISTRY OF SUBSTITUTED DERIVATIVES OF FE3(CO)9(MU-3-S)2 WITH P(SR)3 .1. SYNTHESES AND CRYSTAL-STRUCTURE OF FE3(CO)8[P(SC6H5)3](MU-3-S)2
LIU, QW
WU, BF
HU, X
LIU, ST
YAN, XY
SHI, JQ
ACTA CHIMICA SINICA, 1992, 50 (08) : 778 - 782
[39] Metal substitution in the cluster (mu-H)(2)Fe-3 (mu(3)-Te)(CO)(9) .3. Crystal and molecular structure of [FeMo2(mu(3)-Te)(CO)(7)(eta(5)-C5H5)(2)]
Konchenko, SN
Virovets, AV
Tkachev, SV
Podberezskaya, NV
POLYHEDRON, 1997, 16 (09) : 1549 - 1554
[40] Metal substitution reaction in the cluster [(mu-H)(2)Fe-3(mu(3)-Se)(CO)(9)]. Crystal and molecular structure of [(mu-H)Fe2W(mu(3)-Se)(CO)(8)(eta(5)-C5H5)]
Konchenko, SN
Virovets, AV
Tkachev, SV
Alekseev, VI
Podberezskaya, NV
POLYHEDRON, 1996, 15 (07) : 1221 - 1224

← 1 2 3 4 5 →