ISOTHERMAL FLOW CALORIMETRIC INVESTIGATIONS OF THE D/PD AND H/PD SYSTEMS

被引：37
|
作者：
MCKUBRE, MCH
CROUCHBAKER, S
ROCHA, RC
SMEDLEY, SI
TANZELLA, FL
PASSELL, TO
SANTUCCI, J
机构：
[1] SRI INT,MENLO PK,CA 94025
[2] ELECT POWER RES INST,PALO ALTO,CA 94303
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1994年 / 368卷 / 1-2期
关键词：
D O I：
10.1016/0022-0728(93)03070-6
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Isothermal calorimetric studies of the D/Pd and H/Pd systems have been carried out at high deuterium (hydrogen) loadings (i.e. [D(H)]/[Pd] > 0.9) at approximately 30-degrees-C. Under these conditions, the generation of ''excess power'' was observed in a series of deuterium-based experiments, but not in a hydrogen-based experiment. The results of these experiments enable several (tentative) conclusions to be reached concerning the conditions necessary for the reproducible observation of this anomalous thermal effect.
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页码：55 / 66
页数：12
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