ON THE RHODIUM-CATALYZED FORMATION OF ACETIC-ACID FROM METHYL FORMATE - COMPARISON WITH THE RHODIUM-CATALYZED FORMATION OF ACETIC-ACID BY DIRECT CARBONYLATION OF METHANOL

被引：4
|
作者：
BUB, G [1 ]
HOG, HU [1 ]
机构：
[1] HULS AKTIENGESELL MARL,D-45772 MARL,GERMANY
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1995年 / 95卷 / 01期
关键词：
ACETIC ACID; CARBONYLATION; METHANOL; METHYL FORMATE; RHODIUM;
D O I：
10.1016/1381-1169(94)00161-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In presence of the homogenous Rh/Cr/I catalyst system methyl formate can be isomerized to acetic acid under CO-pressure with high conversion rates and excellent selectivity. This catalyst system has never been applied before for this reaction.
引用
收藏
页码：45 / 52
页数：8
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