BROMONITRILE OXIDE [3+2] CYCLOADDITIONS IN WATER

被引：43
|
作者：
ROHLOFF, JC
ROBINSON, J
GARDNER, JO
机构：
[1] Institute for Organic Chemistry, Syntex Research, Palo Alto
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 22期
关键词：
ACIVICIN; TRANSGLUTAMINASE; CYSTEINE; 4,5-DIHYDROISOXAZOLE; DIBROMOFORMALDOXIME;
D O I：
10.1016/S0040-4039(00)79827-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Bromonitrite oxide can be generated homogeneously in water at acidic pH, allowing efficient [3 + 2] cycloaddition with water soluble olefins and acetylenes. Allylammonium salts react with high regioselectivity and without the need for N-group protection.
引用
收藏
页码：3113 / 3116
页数：4
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