2-(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)-6-(4-nitrophenyl)-4-phenyl-1,3-diazabicyclo[3.1.0]hex-3-ene

被引：3
|
作者：
Albooye, Fereshteh [1 ]
Kiyani, Hamzeh [2 ]
机构：
[1] Islamic Azad Univ, Fac Sci, Damghan Branch, Chem Grp, Damghan 3671639998, Iran
[2] Damghan Univ, Sch Chem, Damghan 36715364, Iran
来源：
MOLBANK | 2013年 / 03期
关键词：
pyrazole; photochromism; bicyclic aziridine; Vilsmeier-Haack reaction;
D O I：
10.3390/M806
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
As a consequence of one-pot, three-component reaction of trans-2-benzoyl-3-(4-nitrophenyl)aziridine with 5-chloro-3-methyl-1-phenyl-1H-pyrazole-4-carbaldehyde and ammonium acetate, 2-(5-chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)-6-(4-nitrophenyl)-4-phenyl-1,3-diazabicyclo[3.1.0]hex-3-ene was achieved in good yield. The desired photochromic compound display interesting photochromic behavior in the crystalline and solution phase. The structure of the newly synthesized photochromic compound was characterized by elemental analysis, H-1-NMR, C-13-NMR and UV-Visible spectral data.
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页数：9
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