(Acridine-kappa N)(pyridine-2,6-dicarboxylato-kappa O-3(2),N,O-6)palladium(II)

被引:1
|
作者
Ha, Kwang [1 ]
机构
[1] Chonnam Natl Univ, Sch Appl Chem Engn, Res Inst Catalysis, Kwangju 500757, South Korea
基金
新加坡国家研究基金会;
关键词
D O I
10.1107/S1600536812011385
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Pd(C7H3NO4)(C13H9N)], the Pd-II ion is four-coordinated in a distorted square-planar environment by one N and two O atoms from the tridentate pyridine-2,6-dicarboxylate (dipic) anionic ligand and one N atom of the acridine (acr) ligand. The dipic and acr ligands are nearly planar [maximum deviation = 0.069 (3) angstrom in dipic and 0.091 (4) angstrom in acr] and the dihedral angle between their mean planes is 58.67 (7)degrees. The Pd-O bond lengths are nearly equal, but the Pd-N bond lengths are slightly different. There is a short C-H center dot center dot center dot O interaction in the molecule involving the two ligands. In the crystal, complex molecules are linked through C-H center dot center dot center dot O interactions, forming a three-dimensional network. There are also a number of intermolecular pi-pi interactions present, the shortest ring centroid-centroid distance being 3.622 (3) angstrom.
引用
收藏
页码:M454 / +
页数:8
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