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- [22] Synthesis and characterization of the allenylidene compounds [Ir(diene)(C=C=CPh(2))(PR(3))]BF4 (diene=1,5-cyclooctadiene, PR(3)=PCy(3); diene equals tetrafluorobenzobarrelene, PR(3)=PCy(3), (PPr3)-Pr-i): The first mixed-ligand complexes of the type [Ir(diene)L(PR(3))](+) containing an unsaturated eta(1)-carbon ligand ORGANOMETALLICS, 1997, 16 (04) : 796 - 799