TRIMETHYLENE DITHIOACETALS OF CARBOHYDRATES .2. D-ARABINOSE, D-GLUCOSE AND D-MANNOSE PROPANE-1,3-DIYL DITHIOACETAL AND THEIR ISOPROPYLIDENE DERIVATIVES

被引：0

作者：

KOLLN, O ^{[1
]}

REDLICH, H ^{[1
]}

FRANK, H ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ORGAN CHEM,D-48149 MUNSTER,GERMANY

来源：

SYNTHESIS-STUTTGART | 1995年 / 11期

关键词：

CARBOHYDRATES; D-ARABINOSE; D-GLUCOSE; D-MANNOSE; ISOPROPYLIDENATION; 1,3-DITHIANE;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of trimethylene dithioacetals of D-arabinose, D-glucose and D-mannose and their isopropylidenation is described. Formation of mono- and diisopropylidene derivatives takes place in moderate to good yields, dependent on the reaction system and the reaction conditions (kinetic and thermodynamic control, respectively). The tendencies for the formation of the individual isopropylidenation pattern are summarized and discussed mainly on the basis of geometric arguments.

引用

页码：1383 / &

共 50 条

[31] Comparative study of C(2) epimerization of D-glucose and D-mannose catalyzed by water soluble organometallic complexes with nitrogen ligands
Kolaric, S
Sunjic, V
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 110 (03) : 181 - 188
[32] The metabolisable hexoses D-glucose and D-mannose enhance the expression of IRS-2 but not of IRS-1 in pancreatic β-cells
Amacker-Françoys, I
Mohanty, S
Niessen, M
Spinas, GA
Trüb, T
EXPERIMENTAL AND CLINICAL ENDOCRINOLOGY & DIABETES, 2005, 113 (08) : 423 - 429
[33] Radical trifluoromethylation of a D-mannose derived ketene dithioacetal.: Synthesis of 2-C-trifluoromethyl derivatives of D-glycero-D-galacto- and D-glycero-D-talo-heptopyranose
Foulard, G
Brigaud, T
Portella, C
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (26): : 9107 - 9113
[34] Preparation of protected 2-deoxy-2-hydroxymethyl-D-mannose and -D-glucose derivatives not involving organometallic reagents
Carbohyd Res, 1-2 (93-98):
[35] A preparation of protected 2-deoxy-2-hydroxymethyl-D-mannose and -D-glucose derivatives not involving organometallic reagents
Malleron, A
David, S
CARBOHYDRATE RESEARCH, 1998, 308 (1-2) : 93 - 98
[36] OPTICAL-ACTIVITY OF COMPOUNDS FORMED BY AMMINO COMPLEXES OF COBALT(III) AND CARBOHYDRATES .2. D-ARABINOSE COMPLEXES
BUNEL, S
IBARRA, C
CALVO, V
MORAGA, E
POLYHEDRON, 1989, 8 (16) : 2023 - 2028
[37] The Antiviral Effects of 2-Deoxy-D-glucose (2-DG), a Dual D-Glucose and D-Mannose Mimetic, against SARS-CoV-2 and Other Highly Pathogenic Viruses
Pajak, Beata
Zielinski, Rafal
Manning, John Tyler
Matejin, Stanislava
Paessler, Slobodan
Fokt, Izabela
Emmett, Mark R.
Priebe, Waldemar
MOLECULES, 2022, 27 (18):
[38] SUGAR MERCAPTALS .13. DERIVATIVES OF 6-AZIDO-6-DEOXY-D-GLUCOSE, -D-MANNOSE, -D-GALACTOSE AND 5-AZIDO-5-DEOXY-L-ARABINOSE
FERNANDE.J
FERNANDE.RG
ANALES DE QUIMICA-INTERNATIONAL EDITION, 1969, 65 (04): : 415 - &
[39] C-2 EPIMERIZATION OF ALDOSES BY CALCIUM-ION IN BASIC SOLUTIONS - A SIMPLE SYSTEM TO TRANSFORM D-GLUCOSE AND D-XYLOSE INTO D-MANNOSE AND D-LYXOSE
YANAGIHARA, R
SOEDA, K
SHIINA, S
OSANAI, S
YOSHIKAWA, S
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993, 66 (08) : 2268 - 2272
[40] HEPTAMOLYBDATE-ION CATALYZED C(2) EPIMERIZATION OF D-MANNOSE TO D-GLUCOSE IN ACETONITRILE-WATER MIXTURES - A KINETIC-STUDY
KOLARIC, S
GELO, M
SANKOVIC, M
SUNJIC, V
JOURNAL OF MOLECULAR CATALYSIS, 1994, 89 (1-2): : 247 - 256

← 1 2 3 4 5 →