TRIMETHYLENE DITHIOACETALS OF CARBOHYDRATES .2. D-ARABINOSE, D-GLUCOSE AND D-MANNOSE PROPANE-1,3-DIYL DITHIOACETAL AND THEIR ISOPROPYLIDENE DERIVATIVES

被引：0

作者：

KOLLN, O ^{[1
]}

REDLICH, H ^{[1
]}

FRANK, H ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ORGAN CHEM,D-48149 MUNSTER,GERMANY

来源：

SYNTHESIS-STUTTGART | 1995年 / 11期

关键词：

CARBOHYDRATES; D-ARABINOSE; D-GLUCOSE; D-MANNOSE; ISOPROPYLIDENATION; 1,3-DITHIANE;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of trimethylene dithioacetals of D-arabinose, D-glucose and D-mannose and their isopropylidenation is described. Formation of mono- and diisopropylidene derivatives takes place in moderate to good yields, dependent on the reaction system and the reaction conditions (kinetic and thermodynamic control, respectively). The tendencies for the formation of the individual isopropylidenation pattern are summarized and discussed mainly on the basis of geometric arguments.

引用

页码：1383 / &

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