1,3-DIPHENYLCYCLOPENTADIENYL COMPLEXES OF SODIUM, INDIUM(I), THALLIUM(I) AND IRON(II) - X-RAY STRUCTURAL-ANALYSIS OF TL(C(5)H(3)PH(2))(THF) AND FE(C(5)H(3)PH(2))(2)

被引：25

作者：

SCHUMANN, H

LENTZ, A

WEIMANN, R

机构：

[1] Institut für Anorganische und Analytische Chemie der Technischen Universität Berlin, Straße des, 17. Juni 135

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期

关键词：

DIPHENYLCYCLOPENTADIENE; SODIUM; INDIUM; THALLIUM; IRON;

D O I：

10.1016/0022-328X(94)05098-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,4-Diphenylcyclopentadiene (1) reacts with TlOC2H5 or NaNH2 to give the corresponding half-sandwich complexes Na(C(5)H(3)Ph(2)) (2) and Tl(C(5)H(3)Ph(2)) (4). 2 reacts with InCl to form In(C(5)H(3)Ph(2)) (3), and 2 as well as 4 react with FeCl2 to form Fe(C(5)H(3)Ph(2))(2) (5). The H-1, C-13 NMR and mass spectra of the new compounds, as well as the X-ray crystal structure analyses of 4 and 5, are reported and discussed.

引用

页码：245 / 252

页数：8

共 50 条

[1] Die 1,3-Diphenylcyclopentadienylkomplexe von Natrium, Indium(I), Thallium(I) und Eisen(II): Roentgenstrukturanalyse von Tl(C5H3Ph2)(THF) und Fe(C5H3Ph2)2
Schumann, H.
Lentz, A.
Weimann, R.
Journal of Organometallic Chemistry, 487 (1-2):
[2] Lutetium complexes with the 1,3-diphenylcyclopentadienyl ligand.: Syntheses and molecular structures of the complexes {(Ph2C5H3)Lu(C2Ph4)(THF)} and {(Ph2C5H3)LuCl2(THF)3}
Roitershtein, D. M.
Minyaev, M. E.
Mikhailyuk, A. A.
Lyssenko, K. A.
Belyakov, P. A.
Antipin, M. Yu.
RUSSIAN CHEMICAL BULLETIN, 2007, 56 (10) : 1978 - 1985
[3] Lutetium complexes with the 1,3-diphenylcyclopentadienyl ligand. Syntheses and molecular structures of the complexes {(Ph2C5H3)Lu(C2Ph4)(THF)} and {(Ph2C5H3)LuCl2(THF)3}
D. M. Roitershtein
M. E. Minyaev
A. A. Mikhailyuk
K. A. Lyssenko
P. A. Belyakov
M. Yu. Antipin
Russian Chemical Bulletin, 2007, 56 : 1978 - 1985
[4] The structure of gold(I) cyclopentadiene complexes: X-ray diffraction studies of (Ph2C5H3)AuPPh3 pentane solvate
Kuzmina, LG
Churakov, AV
Grandberg, KI
Kuzmin, VS
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1997, 23 (03) : 170 - 176
[5] Structure of gold(I) cyclopentadiene complexes: X-ray diffraction studies of (Ph2C5H3)AuPPh3 pentane solvate
Kuz'mina, L.G.
Churakov, A.V.
Grandberg, K.I.
Kuz'min, V.S.
Elektrokhimiya, 1996, 322 (62): : 185 - 192
[6] The Structure of Gold(I) Cyclopentadiene Complexes: X-ray Diffraction Studies of (Ph2C5H3)AuPPh3 Pentane Solvate
Kuz'mina, L. G.
Churakov, A. V.
Grandberg, K. I.
Kuz'min, V. S.
Russian Journal of Coordination Chemistry, 23 (03):
[7] Synthesis, characterization, and single crystal X-ray diffraction studies of cis-Ph2C2H2(η5-C5H4)2Ca(THF)2
Gilbert J. Matare
Kevin M. Kane
Pamela J. Shapiro
Ashwani Vij
Journal of Chemical Crystallography, 1998, 28 : 731 - 734
[8] Synthesis, characterization, and single crystal X-ray diffraction studies of cis-Ph2C2H2(η5-C5H4)2Ca(THF)2
Matare, GJ
Kane, KM
Shapiro, PJ
Vij, A
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1998, 28 (10) : 731 - 734
[9] ORGANOLANTHANIDE AND ORGANOYTTRIUM HYDRIDE CHEMISTRY .9. BIS(1,3-DIMETHYLCYCLOPENTADIENYL)YTTRIUM COMPLEXES - SYNTHESIS AND X-RAY CRYSTALLOGRAPHIC CHARACTERIZATION OF [(1,3-ME2C5H3)2Y(MU-ME)]2, [(1,3-ME2C5H3)2Y(MU-H)]3, AND [(1,3-ME2C5H3)2(THF)Y(MU-H)]2
EVANS, WJ
DRUMMOND, DK
HANUSA, TP
DOEDENS, RJ
ORGANOMETALLICS, 1987, 6 (11) : 2279 - 2285
[10] CRYSTAL AND MOLECULAR STRUCTURES OF DIIODOFERROCENE (C5H3I2.FE.C5H5)
KALUSKI, Z
STRUCHKO.YT
GUSIEV, AI
BULLETIN DE L ACADEMIE POLONAISE DES SCIENCES-SERIE DES SCIENCES CHIMIQUES, 1972, 20 (09): : 875 - &

← 1 2 3 4 5 →