THE CONVERSION OF ISOSAFROLE TO PIPERONAL AND ANETHOLE TO ANISALDEHYDE - ELECTROCHEMICAL ACTIVE MANGANESE-DIOXIDE

被引：21
|
作者：
GRIMSHAW, J
HUA, C
机构：
[1] School of Chemistry, Queen's University, Belfast
来源：
ELECTROCHIMICA ACTA | 1994年 / 39卷 / 04期
关键词：
OXIDATION; MANGANESE DIOXIDE; ISOSAFROLE; PIPERONAL; ANETHOLE;
D O I：
10.1016/0013-4686(94)80092-8
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Non-stoichiometric manganese dioxide prepared electrochemically at room temperature and suspended in dilute sulphuric acid is used to oxidise isosafrole to piperonal in 54% isolated yield. The manganese dioxide-manganese(II) sulphate system can be recycled electrochemically at high current density. It has the further advantage that water-soluble materials derived from the chemical oxidation of isosafrole at a lead dioxide anode leads to further oxidation of the piperonal.
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页码：497 / 499
页数：3
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