DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF BIFUNCTIONAL NEUTRAL ORGANOPHOSPHORUS COMPOUNDS (BNOPC) .2. DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF SYSTEMS WITH BNOPC

被引：0
|
作者：
SHADRIN, AY
BABAIN, VA
KISELEVA, RN
机构：
来源：
RADIOCHEMISTRY | 1993年 / 35卷 / 01期
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中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The diluent effect on the extraction properties of diphenyl(dibutylcarbamoylmethylene)phosphine oxide can be described by the equation 1gD = -9.69 + 22.1 epsilon-1/2epsilon+1 + 4.20 n0(2)-1/n0(2)+1. The correlation coefficient between the calculated and experimental values was 0.96. It is suggested that a water molecule dissolved in the organic phase reacts with H atoms of the bridging methylene.
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页码：30 / 33
页数：4
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