PREPARATION AND CRYSTAL-STRUCTURE OF CSBO2

被引：24
|
作者：
SCHLAGER, M
HOPPE, R
机构：
[1] UNIV GIESSEN,INST ANORGAN & ANALYT CHEM,HEINRICH BUFF RING 58,D-35392 GIESSEN,GERMANY
[2] UNIV GIESSEN,INST ANORGAN & ANALYT CHEM,D-35392 GIESSEN,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 11期
关键词：
CESIUM METABORATE; CSBO2; CRYSTAL STRUCTURE; CALCULATION OF ECON; MEFIR; MAPLE; CHARDI;
D O I：
10.1002/zaac.19946201106
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Colourless single crystals of CsBO2 have been prepared from intimate mixtures of CsO0.57 and B2O3 (Cs:B = 3.2:1.0; 600 degrees C, 38 d). The structure determination from four-circle diffractometer data (MoK<(alpha)over bar>, 443 I-o (h k l), R = 3.1%, R(w) = 2.0%) confirms the isotypy with NaBO2 and KBO2: space group R (3) over bar c; a = 1363.7(2) pm, c = 836.5(2) pm; Z = 18. A characteristic structure unit is the planar cyclic anion [B3O6](3-). Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR), the Madelung Part of Lattice Energy (MAPLE) and the Charge Distribution (CHARDI) are calculated and discussed.
引用
收藏
页码：1867 / 1871
页数：5
相关论文
共 50 条
  • [21] THE PREPARATION AND CRYSTAL-STRUCTURE OF 2-PHENOXYPROPENOIC ACID
    CAMPBELL, M
    MCLEISH, MJ
    LYNCH, DE
    SMITH, G
    BYRIEL, KA
    KENNARD, CHI
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1992, 45 (12) : 2061 - 2066
  • [22] PREPARATION AND CRYSTAL-STRUCTURE OF LI2SB
    MULLER, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1977, 32 (03): : 357 - 359
  • [23] THE THERMODYNAMIC PROPERTIES OF CESIUM METABORATE CSBO2 FROM 5 TO 1000-K
    CORDFUNKE, EHP
    KONINGS, RJM
    WESTRUM, EF
    THERMOCHIMICA ACTA, 1988, 128 : 31 - 38
  • [24] MASS-SPECTROMETRIC STUDY OF THE THERMODYNAMIC PROPERTIES OF (XRBBO2+(1-X)CSBO2)
    KATO, Y
    ASANO, M
    HARADA, T
    MIZUTANI, Y
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1992, 24 (10): : 1033 - 1038
  • [25] PREPARATION AND CRYSTAL-STRUCTURE OF ZIRCONIUM NITRIDEFLUORIDE
    JUNG, W
    JUZA, R
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1973, 399 (02): : 129 - 147
  • [26] DIBROMOMETHYLSULFONIUM SALTS - PREPARATION AND CRYSTAL-STRUCTURE
    MINKWITZ, R
    PRENZEL, H
    WERNER, A
    PREUT, H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 562 (07): : 42 - 48
  • [27] PREPARATION AND CRYSTAL-STRUCTURE OF KNAO AND RBNAO
    SABROWSKY, H
    SCHROER, U
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1982, 37 (07): : 818 - 819
  • [28] PREPARATION AND CRYSTAL-STRUCTURE OF COMPOUND UASSB
    TROJKO, R
    DESPOTOVIC, Z
    JOURNAL OF NUCLEAR MATERIALS, 1977, 67 (1-2) : 105 - 108
  • [29] PREPARATION AND CRYSTAL-STRUCTURE OF A NEW HYDROXYCHROMATE
    RIOU, A
    BULLETIN DE LA SOCIETE FRANCAISE MINERALOGIE ET DE CRISTALLOGRAPHIE, 1974, 97 (06): : 405 - 410
  • [30] PREPARATION AND CRYSTAL-STRUCTURE OF LITHIUMHYDROGENSULFIDE, LIHS
    JACOBS, H
    KIRCHGASSNER, R
    BOCK, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1989, 569 (02): : 111 - 116
12345