AMPLITUDES OF GAMMA-DETECTED NMRON SPIN-ECHO SIGNALS

被引:2
|
作者
ISBISTER, DJ
CHAPLIN, DH
机构
[1] Department of Physics, University College, The University of New South Wales, Australian Defence Force Academy, Canberra, ACT
来源
HYPERFINE INTERACTIONS | 1990年 / 62卷 / 03期
关键词
D O I
10.1007/BF02397697
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The amplitudes of the spin echo and the baseline components of gamma detected NMRON signals have been calculated for the pure Zeeman case using a density matrix approach. Optimum turn angles and the separate and combined influences of line broadening and skin effect, appropriate to bulk ferromagnetic metals, are examined. For narrow line, zero skin effect samples, the triple pulse sequence (cos-1(1/square-root3)) - 180-degrees - (180-degrees - cos-1(1/square-root3)) affords the largest principal echo. However, its advantage is diminished with the introduction of either line broadening or skin effect and is subsequently lost when both these effects are included or either becomes severe. The skin effect distortion of the spin echo signal can dominate over intermediate-to-broad line distortions, for that range of experimental conditions generally applicable to metallic ferromagnetic hosts.
引用
收藏
页码:181 / 198
页数:18
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