A NEW-TYPE OF WATER-SOLUBLE PHOSPHINE FOR BIPHASIC CATALYSIS

被引：21

作者：

MERCIER, F ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,CNRS,URA 1499 CDPH,HETEROELEMENTS & COORDINAT LAB,F-91128 PALAISEAU,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 462卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83346-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the [4 + 2] dimer of 3,4-dimethyl-2H-phosphole with maleic anhydride in boiling THF gives the 2H-phosphole-maleic anhydride [4 + 2] endocyclo-adduct in 60% yield. Upon treatment with sodium hydroxide, this cyclo-adduct is transformed into the sodium salt of 3,4-dimethyl-1-phospha-2-norbornene-5,6-dicarboxylic acid which is very soluble in water (greater than or equal to 300 g/l) and is not extracted from water by organic solvents such as toluene and dichloromethane.

引用

页码：103 / 106

页数：4

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