OPTICALLY PURE (S)-4 AND (R)-4,5-DIHYDRO-3H-4-METHYLDINAPHTH[2,1-C-1',2'-E]AZEPINES - APPLICATION TO THE SYNTHESIS OF NEW BIDENTATE LIGANDS WITH AXIAL ASYMMETRY

被引：11

作者：

STARA, IG ^{[1
]}

STARY, I ^{[1
]}

ZAVADA, J ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI, INST ORGAN CHEM & BIOCHEM, CS-16610 PRAGUE 6, CZECHOSLOVAKIA

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 11期

关键词：

D O I：

10.1016/0957-4166(92)80007-J

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Easily available ephedrinium salts (S,1R,2S)- and (R,1R,2S)-2 on treatment with alkoxide base afford enantiomerically pure dihydroazepines (S)- and (R)-1, respectively, in quantitative yields. Cleavage of the corresponding dihydroazepinium quaternary salts (S)- and (R)-4 with N- and S-nucleophiles provides a simple approach to a new series of 1,1'-binaphthalene ligands with two different donor groups in 2,2'-positions.

引用

页码：1365 / 1368

页数：4

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