A SIMPLE SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DINUCLEAR DIPHOSPHIDO-BRIDGED PALLADIUM(I) COMPLEX [PD(P(TERT-BU)2H)(MU-P(TERT-BU)2)]2

被引：49

作者：

LEONI, P

SOMMOVIGO, M

PASQUALI, M

SABATINO, P

BRAGA, D

机构：

[1] DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

[2] DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 423卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)83119-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

UV irradiation of Pd(P(t)Bu3)2 in n-hexane or THF gives the diamagnetic dinuclear complex [Pd(P(t)Bu2H)(mu-P(t)Bu2)]2, 2-methylpropene, and hydrogen. The complex was also obtained from the reaction of Pd(eta(5)-C5H5)(eta(3)-C3H5) with P(t)Bu2H in toluene. Its crystal and molecular structure were determined by an X-ray diffraction study. Each Pd bears a terminal P(t)Bu2H ligand and the two metal centers are bridged by two phosphido ligands.

引用

页码：263 / 270

页数：8

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