MAGNETIC AND ELECTRICAL BEHAVIORS OF C-60(TDAE) SINGLE-CRYSTAL

被引：13
|
作者：
SUZUKI, A
SUZUKI, T
MARUYAMA, Y
机构：
[1] The Graduate University for Advanced Studies, Institute for Molecular Science, Okazaki, 444, Myodaiji
来源：
SOLID STATE COMMUNICATIONS | 1995年 / 96卷 / 05期
关键词：
MAGNETICALLY ORDERED MATERIALS; FULLERENES; ELECTRONIC TRANSPORT;
D O I：
10.1016/0038-1098(95)00456-4
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Significant size of single crystals of C-60(TDAE), where TDAE is tetrakis(dimethylamino)ethylene, have been prepared from a toluene solution for the first time by a diffusion method. The resulting conglomerate of black colored needles is found to consist of single crystals by X-ray diffraction analysis. A resistivity of 1.1 x 10(5) Omega cm at room temperature and an activation energy of 0.4 similar to 0.8 eV suggest that an obtained C,(TDAE) crystal is not metallic but semiconducting. The crystals do not show a ferromagnetic behavior but Pauli- and Curie-Weiss paramagnetism with a negative Weiss constant, theta = -0.44 K. It was found that the difference in the magnetic properties between crystal and powder samples may originate from the change of the lattice constants.
引用
收藏
页码：253 / 257
页数：5
相关论文
共 50 条
  • [31] Proton NMR in a TDAE-C-60 single crystal
    Arcon, D
    Dolinsek, J
    Blinc, R
    Pokhodnia, K
    Omerzu, A
    Mihailovic, D
    Venturini, P
    PHYSICAL REVIEW B, 1996, 53 (21): : 14028 - 14031
  • [32] VIBRATIONAL ANALYSIS OF IR REFLECTION-TRANSMISSION FROM SINGLE-CRYSTAL C-60
    WINKLER, R
    PICHLER, T
    KUZMANY, H
    ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1994, 96 (01): : 39 - 45
  • [33] EPITAXIAL-GROWTH OF SINGLE-CRYSTAL C-60 FILMS ON GAAS(111) SUBSTRATES
    YONEDA, Y
    SAKAUE, K
    TERAUCHI, H
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1994, 63 (10) : 3560 - 3563
  • [34] Negative photoconductance in a single crystal of C-60
    Ishijima, Y
    Ishiguro, T
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1996, 65 (06) : 1574 - 1577
  • [35] Electrical transport measurements on TDAE-C60 single crystals
    Omerzu, A.
    Mihailovic, D.
    Biskup, N.
    Milat, O.
    Tomic, S.
    Synthetic Metals, 85 (1-3): : 1723 - 1724
  • [36] ROTATIONAL ORDERING TRANSITION IN SINGLE-CRYSTAL C-60 STUDIED BY RAMAN-SPECTROSCOPY
    VANLOOSDRECHT, PHM
    VANBENTUM, PJM
    MEIJER, G
    PHYSICAL REVIEW LETTERS, 1992, 68 (08) : 1176 - 1179
  • [37] INELASTIC NEUTRON-SCATTERING STUDY OF THE EXTERNAL VIBRATIONS IN SINGLE-CRYSTAL C-60
    PINTSCHOVIUS, L
    RENKER, B
    GOMPF, F
    HEID, R
    CHAPLOT, SL
    HALUSKA, M
    KUZMANY, H
    PHYSICAL REVIEW LETTERS, 1992, 69 (18) : 2662 - 2665
  • [38] PHASE-TRANSITION OF SINGLE-CRYSTAL C-60 FILMS ON GAAS(III) SUBSTRATES
    YONEDA, Y
    SAKAUE, K
    TERAUCHI, H
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1994, 63 (12) : 4290 - 4293
  • [39] Magnetic properties of TDAE-C-60 single crystal and powder samples: The influence of thermal annealing
    Jaglicic, Z
    Trontelj, Z
    Luznik, J
    Pirnat, J
    Blinc, R
    SOLID STATE COMMUNICATIONS, 1997, 101 (08) : 591 - 595
  • [40] Electrical transport measurements om TDAE-C-60 single crystals
    Omerzu, A
    Mihailovic, D
    Biskup, N
    Milat, O
    Tomic, S
    SYNTHETIC METALS, 1997, 85 (1-3) : 1723 - 1724
12345