Electrochemical Properties of Bismuth Oxide Films on Titanium Formed by Plasma Electrolytic Oxidation

被引：0

作者：

Lapina, Antonina S. ^{[1
]}

Marinina, Galina I. ^{[1
]}

Vasilyeva, Marina S. ^{[1
]}

Kondrikov, Nicolai B. ^{[1
]}

Schitovskaya, Elena V. ^{[1
]}

Fedorets, Alexander N. ^{[1
]}

Korochentsev, Vladimir V. ^{[1
]}

Os'mushko, Ivan S. ^{[1
]}

机构：

[1] Far Eastern Fed Univ, Sch Nat Sci, 8 Suhanova Str, Vladivostok 690950, Russia

来源：

JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2014年 / 7卷 / 03期

关键词：

bismuth oxide; plasma electrolytic oxidation; metal oxide electrodes;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bismuth oxide layers on a titanium are formed by a plasma electrolytic oxidation (PEO) method from electrolytes containing complex ions EDTA-Bi3+. Electrochemical characteristics - exchange currents, transport coefficients alpha and beta, a and b coefficients in Tafel's equation are defined. For the obtained systems occurrence of an analytical signal at complexometric titration of salts of Fe (III) is established. The structural features of surface electrodes have been investigated by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) techniques. Correlation between morphology, structure of a surface and electrochemical properties of samples is found.

引用

页码：412 / 423

页数：12

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