PREPARATION, B-11 NMR AND VIBRATIONAL-SPECTRA OF CIS-MONOCYANOMONONITROTETRAHYDRO-CLOSO-HEXABORATE(2-), CIS-[B6H4(CN)(NO2)(2-), CIS-MU-NITROSO-BIS(MONOCYANOTETRAHYDRO-HEXABORATE)(3-), CIS-[(CN)B6H4(NO)B6H4(CN)](3-) AND THE CRYSTAL-STRUCTURE OF [AS(C6H5)(4)](2)-CIS-[B6H4(CN)(NO2)]

被引：0

作者：

FRANKEN, A ^{[1
]}

PREETZ, W ^{[1
]}

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,D-24098 KIEL,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1995年 / 50卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By electrochemical oxidation of [B6H5(CN)](2-) in the presence of nitrite ions and of the base DBU in dichloromethane solution Cis-[B6H4(CN)(NO2)](2-) and cis- [(CN)B6H4(NO)B6H4(CN)](3-) are formed and can be isolated by ion exchange chromatography on diethylaminoethyl cellulose. The crystal structure of the tetraphenylarsonium salt has been determined by single crystal X-ray diffraction analysis. [As(C6H5)(4)](2)-cis-[B6H4(CN)(NO2)] is monoclinic, space group P2(1)/a with a = 20.343(5), b = 10.896(2), c = 21.572(5) Angstrom and beta = 107.30(2)degrees. The B-11 NMR spectra are consistent with disubstituted octahedral B-6 cages with local C-2v symmetry. The IR and Raman spectra exhibit characteristic NO2, NO, CN, BH, and B-6 vibrations.

引用

页码：1362 / 1368

页数：7

共 50 条

[31] Iron Salts with the Tetracyanidoborate Anion: [FeIII(H2O)6][B(CN)4]3, Coordination Polymer [FeII(H2O)2{κ2N[B(CN)4]}2], and [FeII(DMF)6][B(CN)4]2
Nitschke, Christian
Koeckerling, Martin
INORGANIC CHEMISTRY, 2011, 50 (10) : 4313 - 4321
[32] Preparation, B-11, C-13, H-1 NMR and vibrational spectra of phenylundecahydro-closo-dodecaborate(2-) and crystal structure of [As(C6H5)(4)](2)[(C6H5)B12H11]
Koch, T
Preetz, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (08): : 935 - 938
[33] Synthesis, spectra and crystal structures of two RuII complexes with polypyridyl ligands:: cis-[Ru(bpy)2(4,4′-bpy)Cl](PF6)•H2O and cis-[Ru(phen)2(CH3CN)2] (PF6)2
Du, M
Ge, XJ
Liu, H
Bu, XH
JOURNAL OF MOLECULAR STRUCTURE, 2002, 610 (1-3) : 207 - 213
[34] PREPARATION, VIBRATIONAL-SPECTRA AND NORMAL-COORDINATE ANALYSIS OF THE D AND C-13 ISOTOPOMERES OF THE METHYLPENTAHYDRO-CLOSO-HEXABORATE [B6H5(CH3)](2-) AND THE CRYSTAL-STRUCTURE OF [P(C6H5)(4)][B6H6(CH3)]
BAURMEISTER, J
FRANKEN, A
PREETZ, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (04): : 623 - 629
[35] THE CRYSTAL-STRUCTURE OF TETRAPHENYLPHOSPHONIUM MONOIODOHEXAHYDRO-CLOSO-HEXABORATE [P(C6H5)(4)][B6H6I]
PREETZ, W
SONNAK, D
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (12): : 1809 - 1812
[36] PREPARATION OF MU-NITROSO-BIS(PENTAHYDRO-CLOSO-HEXABORATE)(3-) AND CRYSTAL-STRUCTURE OF CS-3[B6H5(NO)B6H5]
FRANKEN, A
PREETZ, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (09): : 1263 - 1266
[37] Synthesis of cis- and trans-[M(CN)2(1-CH3-C6H10-NC)4] (M = Fe, Ru) and crystal structure of trans-[Ru(CN)2(1′-CH3-C6H10-NC)4]
Sterzik, Anke
Schwierz, Markus
Goerls, Helmar
Imhof, Wolfgang
INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (01) : 119 - 122
[38] PREPARATION, B-11, C-13, SI-29 NMR AND VIBRATIONAL-SPECTRA OF TRIMETHYLSILYLMETHYL-HEXAHYDRO-CLOSO-HEXABORATE, [B6H6(CH2SI(CH3)(3))](-) AND THE CRYSTAL-STRUCTURE OF [P(C6H5)(4)][B6H6(CH2SI(CH3)(3))]
BAURMEISTER, J
FRANKEN, A
PREETZ, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (07): : 1025 - 1029
[39] PREPARATION, B-11 NMR AND VIBRATIONAL-SPECTRA OF THE OCTAHEDRAL CLOSO-BORATE ANIONS B6H6(2-), B6CL6(2-), B6BR6(2-) B6I6(2-)
PREETZ, W
FRITZE, J
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1984, 39 (11): : 1472 - 1477
[40] PREPARATION, B-11 NMR AND VIBRATIONAL-SPECTRA OF AMINOHEXAHYDRO-CLOSO-HEXABORATE(1-), [B6H6(NH2)](-), AND THE CRYSTAL-STRUCTURE OF CS[B6H6(NH2)]CENTER-DOT-H2O
FRANKEN, A
PREETZ, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (01): : 11 - 14

← 1 2 3 4 5 →