ASYMMETRICAL SYNTHESIS OF ORGANOMETALLIC ANALOGS OF NATURAL COMPOUNDS .8. REACTIONS OF PENTAFLUOROBENZALDEHYDE WITH THE NI(II) COMPLEX OF A SCHIFF-BASE OF GLYCINE AND (S)-2-[N-(BENZYLPROLYL)AMINO]BENZOPHENONE

被引：1

作者：

SOLOSHONOK, VA ^{[1
]}

SVISTUNOVA, NY ^{[1
]}

KUKHAR, VP ^{[1
]}

KUZMINA, NA ^{[1
]}

BELOKON, YN ^{[1
]}

机构：

[1] UKRAINIAN ACAD SCI,BIOORGAN CHEM & PETR CHEM INST,252028 KIEV,UKRAINE,USSR

来源：

BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 03期

关键词：

ASYMMETRICAL SYNTHESIS; PENTAFLUOROBENZALDEHYDE; SCHIFF BASE; FLUORINE-SUBSTITUTED BETA-PHENYLSERINES;

D O I：

10.1007/BF00863081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of pentafluorobenzaldehyde with a Ni(II) complex of a Schiff base formed from glycine and (S)-2-[N-(benzylprolyl)amino]benzophenone yields, depending on the reaction conditions, the hitherto unknown, disastereo and enantiomerically pure amino acids 2R,3S-beta-(4-methoxytetrafluorophenyl)serine, 2S,3R-beta-(4-methoxytetrafluorophenyl) serine, 2S,3S-beta-(pentafluorophenyl)serine, and 2S,3R-beta-(pentafluorophenyl)serine.

引用

页码：540 / 545

页数：6

共 28 条

[21] Advanced asymmetric synthesis of (1R,2S)-1-amino-2-vinylcyclopropanecarboxylic acid by alkylation/cyclization of newly designed axially chiral Ni(II) complex of glycine Schiff base
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[22] Advanced asymmetric synthesis of (1R,2S)-1-amino-2-vinylcyclopropanecarboxylic acid by alkylation/cyclization of newly designed axially chiral Ni(II) complex of glycine Schiff base
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Shu, Shuangjie
Takeda, Ryosuke
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Izawa, Kunisuke
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Soloshonok, Vadim A.
Liu, Hong
AMINO ACIDS, 2016, 48 (04) : 973 - 986
[23] ASYMMETRIC-SYNTHESIS OF (2S,3R)-2-AMINOMETHYL-3-HYDROXY-3-PHENYLPROPANOIC AND (2S,3S)-2-AMINOMETHYL-3-HYDROXY-3-PHENYLPROPANOIC ACIDS VIA A CHIRAL NIII COMPLEX OF A SCHIFF-BASE PREPARED FROM BETA-ALANINE AND (S)-2-[-N-(N'-BENZYL)PROLYLAMINO]BENZOPHENONE
BELOKON, YN
MOTSISHKITE, SM
MALEEV, VI
ORLOVA, SA
IKONNIKOV, NS
SHAMURATOV, EB
BATSANOV, AS
STRUCHKOV, YT
MENDELEEV COMMUNICATIONS, 1992, (03) : 89 - 91
[24] SYNTHESIS AND STRUCTURE OF TRANS-BIS[[PENTACARBONYL(N-(2-((DIPHENYLPHOSPHINO)-AMINO)ETHYL)SALICYLALDIMINATO-P)]MOLYBDENUM(0)-N,O]-COPPER(II) - A NOVEL TRIMETALLIC COMPLEX WITH A MIXED P-DONOR-SCHIFF-BASE BRIDGING LIGAND
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ZELL, AL
EINSPAHR, H
INORGANIC CHEMISTRY, 1986, 25 (17) : 2923 - 2925
[25] Synthesis, anticancer and larvicidal activities of a novel Schiff base ligand, 3-((2-((1-(4-hydroxyphenyl)ethylidene)amino)ethyl)imino)-N-(p-tolyl) butanamide and its Mn(II), Fe(III), Co(II), Ni(II) and Zn(II) complexes
Kumar, K. Subin
Reena, V. N.
Aravindakshan, K. K.
RESULTS IN CHEMISTRY, 2021, 3
[26] Why is monoalkylation versus bis-alkylation of the Ni(II) complex of the Schiff base of (S)-N-(2-benzoylphenyl)-1-benzylpyrrolidine-2-carboxamide and glycine so selective? MP2 modelling and topological QTAIM analysis of chiral metallocomplex synthons of α-amino acids used for the preparation of radiopharmaceuticals for positron emission tomography
Alexander Popkov
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Journal of Radioanalytical and Nuclear Chemistry, 2010, 286 : 829 - 833
[27] Why is monoalkylation versus bis-alkylation of the Ni(II) complex of the Schiff base of (S)-N-(2-benzoylphenyl)-1-benzylpyrrolidine-2-carboxamide and glycine so selective? MP2 modelling and topological QTAIM analysis of chiral metallocomplex synthons of α-amino acids used for the preparation of radiopharmaceuticals for positron emission tomography
Popkov, Alexander
Breza, Martin
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2010, 286 (03) : 829 - 833
[28] Long-range J(15N,13C) and J(13C,13C) coupling constants via the metal atom in 13C NMR spectra of square-planar Ni(II) complexes of the Schiff base of (S)-2-(N-benzylprolyl)aminobenzophenone and 13C-1-, 13C-2- or 15N-labelled glycine
Jirman, J
Nádvornik, M
Sopková, J
Popkov, A
MAGNETIC RESONANCE IN CHEMISTRY, 1998, 36 (05) : 351 - 355

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