HOMOPOLYMER SURFACTANT FOR IMMISCIBLE HOMOPOLYMER BLENDS

被引:17
|
作者
NOOLANDI, J
机构
[1] Xerox Research Centre of Canada, Mississauga, Ontario, L5K 2L1
关键词
D O I
10.1002/mats.1994.040030108
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
It is commonly believed that block copolymers are the only type of polymeric surfactants available for incompatible homopolymers(1)). We explore the conditions for which a homopolymer will also lower the surface tension between two incompatible homopolymers by lowering the enthalpic contribution to the interfacial free energy, noting that the resulting three-component interface will not necessarily have the same mechanical strength as a block copolymer-homopolymer interface.
引用
下载
收藏
页码:91 / 93
页数:3
相关论文
共 50 条
  • [31] MISCIBILITY AND MORPHOLOGY IN BLOCK COPOLYMER HOMOPOLYMER BLENDS
    JIANG, M
    XIE, HK
    PROGRESS IN POLYMER SCIENCE, 1991, 16 (06) : 977 - 1026
  • [32] MODEL FOR MICELLE FORMATION IN COPOLYMER HOMOPOLYMER BLENDS
    KAO, CHR
    DELACRUZ, MO
    JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (11): : 8284 - 8293
  • [33] Composition fluctuations in homopolymer blends and diblock copolymers
    Frielinghaus, H
    Mortensen, K
    Almdal, K
    PHYSICA B, 2000, 276 : 375 - 376
  • [34] THEORY OF BLOCK COPOLYMER-HOMOPOLYMER BLENDS
    NOOLANDI, J
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1985, 89 (11): : 1147 - 1154
  • [35] Phase behavior of ternary blends of diblock copolymer with homopolymer blends
    Huh, J
    Jo, WH
    JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (21): : 9920 - 9926
  • [36] Mesoscopic simulation of asymmetric-copolymer/homopolymer blends:: Microphase morphological modification by homopolymer chains solubilization
    Soto-Figueroa, Cesar
    Vicente, Luis
    Martinez-Magadan, Jose-Manuel
    Rodriguez-Hidalgo, Maria-del-Rosario
    POLYMER, 2007, 48 (13) : 3902 - 3911
  • [37] Distribution of homopolymer in lamellar self-assembled diblock copolymer/homopolymer blends involving specific interactions
    Klymko, T.
    Subbotin, A.
    ten Brinke, G.
    MACROMOLECULES, 2007, 40 (08) : 2863 - 2871
  • [38] The effects of copolymer architecture on phase separation dynamics of immiscible homopolymer blends in the presence of copolymer: a Monte Carlo simulation
    Ko, MJ
    Kim, SH
    Jo, WH
    POLYMER, 2000, 41 (16) : 6387 - 6394
  • [39] Bidirectional mapping between self-consistent field theory and molecular dynamics: Application to immiscible homopolymer blends
    Sewell, Thomas D.
    Rasmussen, Kim O.
    Bedrov, Dmitry
    Smith, Grant D.
    Thompson, Russell B.
    JOURNAL OF CHEMICAL PHYSICS, 2007, 127 (14):
  • [40] SOME ASPECTS OF MORPHOLOGIES AND INTERFACES IN COPOLYMER/HOMOPOLYMER BLENDS
    江明
    曹宪一
    于同隐
    Chinese Journal of Polymer Science, 1988, (04) : 345 - 352