SYNTHESIS OF BETA-SUBSTITUTED PORPHYRINS USING PALLADIUM-CATALYZED REACTIONS

被引：48
|
作者：
ALI, H [1 ]
VANLIER, JE [1 ]
机构：
[1] UNIV SHERBROOKE,FAC MED,MRC,RADIAT SCI GRP,SHERBROOKE J1H 5N4,PQ,CANADA
来源：
TETRAHEDRON | 1994年 / 50卷 / 41期
基金：
英国医学研究理事会;
关键词：
BETA-HALOGENATED PORPHYRINS; PALLADIUM CATALYZED REACTION; COUPLING REACTION; TERMINAL ACETYLENIC DERIVATIVE;
D O I：
10.1016/S0040-4020(01)89306-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The palladium(II)-catalysed carbon-carbon-coupling reaction (Heck reaction) between a variety of metalated beta-monohalosubstituted porphyrins (2-bromotetraphenylporphyrin, 2-bromo-3,7,8,12,13,17,18-heptaethylporphyrin, and 3(8)monoiodo-deuterporphyrin IX dimethyl ester) and a series of terminally substituted acetylenic derivatives, is reported. A few disubstituted porphyrin analogs were also synthesized using the corresponding beta-dihalogenated porphyrin precursors.
引用
收藏
页码：11933 / 11944
页数：12
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