BOROSILICATE SYNTHESIS IN NONAQUEOUS SOLVENT AND ITS ACTIVITY FOR N-ICOSANE CRACKING

被引：6
|
作者：
ASAOKA, H
机构：
[1] Division of Chemistry, General Education Department, Niigata University, Niigata, 950-21
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 68卷 / 03期
关键词：
D O I：
10.1016/0304-5102(91)80089-L
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A typical synthesis of borosilicate in anhydrous pyridine consists of the preparation of a gel comprising a source of tetraethyl orthosilicate (Si(OEt)4) and orthoboric acid. To assess catalytic cracking activity, borosilicate was tested for n-icosane (C20H42) cracking. The cracking activity and reduced coking propensity are consistent with the weak acidity of borosilicate. Characterization of the catalyst was carried out using high resolution solid state magic angle spinning (MAS) B-11 and Si-29 NMR, and infrared (IR) spectroscopy.
引用
收藏
页码：301 / 311
页数：11
相关论文
共 50 条
  • [41] Synthesis of N-hydroxysuccinimidyl benzoate and its structural insight into labeling activity of fluorescent probes
    Meng, Qinghua
    Zhang, Wanbin
    Sun, Zhicheng
    Zhang, Haifeng
    Yu, Meijuan
    DYES AND PIGMENTS, 2007, 75 (01) : 166 - 169
  • [42] Y zeolite from kaolin taken in Yen Bai-Vietnam: synthesis, characterization and catalytic activity for the cracking of n-heptane
    Ta Ngoc Don
    Vu Dao Thang
    Pham Thanh Huyen
    Pham Mirth Hao
    Nguyen Khanh Dieu Hong
    NEW DEVELOPMENT AND APPLICATION IN CHEMICAL REACTION ENGINEERING, 4TH ASIA-PACIFIC CHEMICAL REACTION ENGINEERING SYMPOSIUM (APCRE 05), 2006, 159 : 197 - 200
  • [43] Green and facile synthesis of binder-free shaped EU-1 zeolite and its application in n-hexane cracking
    Li, Yaoning
    Wang, Yaquan
    Bu, Lingzhen
    Su, Xuemei
    Zhang, Xian
    Sang, Juncai
    Ren, Guomei
    Wen, Muhan
    JOURNAL OF POROUS MATERIALS, 2025,
  • [44] Synthesis of N,N,N′,N′-Tetraoctyl-3-oxapentane-1,5-diamide (TODGA) and Its Steam Thermolysis-Nitrolysis as a Nuclear Waste Solvent Minimization Method
    Dicholkar, Deepak D.
    Kumar, Pradipta
    Heer, Parminder Kaur
    Gaikar, Vilas G.
    Kumar, Shekhar
    Natarajan, R.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (07) : 2457 - 2469
  • [45] Synthesis of zeolite ZSM-57 and its catalytic evaluation for the 1-butene skeletal isomerization and n-octane cracking
    Lee, SH
    Lee, DK
    Shin, CH
    Paik, WC
    Lee, WM
    Hong, SB
    JOURNAL OF CATALYSIS, 2000, 196 (01) : 158 - 166
  • [46] Novel N-Alkylbenzimidazole-Ruthenium (II) complexes: Synthesis and catalytic activity of N-alkylating reaction under solvent-free medium
    Sahin, Neslihan
    Ozdemir, Namik
    Gurbuz, Nevin
    Ozdemir, Ismail
    APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (02)
  • [47] Di-n-amyl L-tartrate-boric acid complex chiral selector in situ synthesis and its application in chiral nonaqueous capillary electrophoresis
    Wang, Li-Juan
    Hu, Shao-Qiang
    Guo, Qiao-Ling
    Yang, Geng-Liang
    Chen, Xing-Guo
    JOURNAL OF CHROMATOGRAPHY A, 2011, 1218 (09) : 1300 - 1309
  • [48] Synthesis of N,C,C-trilithio-2,5-diallyl-pyrrole and its solvent-controlled reactions with electrophiles
    Lab. für Anorganische Chemie, Universität Bayreuth, Postfach 101251, D-95440 Bayreuth, Germany
    Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1997, 52 (03): : 427 - 430
  • [49] In silico Assessment of Biological Activity and Ozonolytic Synthesis of Platanic Acid and Its Derived N-Acylhydrazones
    E. R. Belyaeva
    G. Yu. Ishmuratov
    Russian Journal of General Chemistry, 2023, 93 : S124 - S130
  • [50] Concise Synthesis of Pseudane IX, Its N-Oxide, and Novel Carboxamide Analogs with Antibacterial Activity
    Angelov, Plamen
    Mollova-Sapundzhieva, Yordanka
    Alonso, Francisco
    Goranov, Bogdan
    Nedialkov, Paraskev
    Bachvarova, Denitsa
    MOLECULES, 2024, 29 (15):
12345