REACTIONS OF ORGANYLHALOSILANES WITH 1,1,3,3-TETRA-METHYLDISILAZANE AND HEXAMETHYLDISILAZANE

被引:2
|
作者
BASENKO, SV
GEBEL, IA
TORYASHINOVA, DD
VITKOVSKII, VY
MIRSKOV, RG
VORONKOV, MG
机构
[1] Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR
关键词
D O I
10.1007/BF00961370
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organylchlorosilanes, and also SiCl4, decompose 1,1,3,3-tetra- and hexamethyl-disilazanes with formation of hitherto unknown organylchlorosilazanes of general formulas R4-nSiCln-1NHSiH(CH3)2 and R4-nSiCln-1NHSi(CH3)3 (n = 2-4) in yields of 54-98%. The IR and mass spectra of the prepared compounds were studied.
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页码:1039 / 1042
页数:4
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