THE CRYSTAL-STRUCTURE OF MOO2CL2[(CH3OCH2CH2)2P(O)CH2CH2P(O)(CH2CH2OCH3)2]

被引：7

作者：

HERBOWSKI, A

LIS, T

DEUTSCH, EA

机构：

[1] WROCLAW UNIV,INST CHEM,PL-50383 WROCLAW,POLAND

[2] UNIV CINCINNATI,BCRC,CINCINNATI,OH 45221

[3] UNIV CINCINNATI,DEPT CHEM,CINCINNATI,OH 45221

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 460卷 / 01期

关键词：

D O I：

10.1016/0022-328X(93)80354-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,2-Bis[bis(methoxyethyl)phosphino]ethane dioxide (tmepeO2) (1) and its molybdenum(VI) complex, MoO2Cl2 (tmepeO2) (2) are resistant to acidic hydrolysis in ambient temperatures. The crystal structure of 2 has been determined by X-ray diffraction methods and refined by a full-matrix least-squares technique to R = 0.0395 for 2393 independent non-zero reflections. Crystals are monoclinic, space group P2(1)/c, with four complex molecules in the unit cell of dimensions: a = 14.655(13), b = 8.298(10), c = 20.644(28) angstrom, beta = 108.97(9)-degrees.

引用

页码：25 / 30

页数：6

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