THE CRYSTAL-STRUCTURE OF MOO2CL2[(CH3OCH2CH2)2P(O)CH2CH2P(O)(CH2CH2OCH3)2]

被引：7
|
作者：
HERBOWSKI, A
LIS, T
DEUTSCH, EA
机构：
[1] WROCLAW UNIV,INST CHEM,PL-50383 WROCLAW,POLAND
[2] UNIV CINCINNATI,BCRC,CINCINNATI,OH 45221
[3] UNIV CINCINNATI,DEPT CHEM,CINCINNATI,OH 45221
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 460卷 / 01期
关键词：
D O I：
10.1016/0022-328X(93)80354-E
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
1,2-Bis[bis(methoxyethyl)phosphino]ethane dioxide (tmepeO2) (1) and its molybdenum(VI) complex, MoO2Cl2 (tmepeO2) (2) are resistant to acidic hydrolysis in ambient temperatures. The crystal structure of 2 has been determined by X-ray diffraction methods and refined by a full-matrix least-squares technique to R = 0.0395 for 2393 independent non-zero reflections. Crystals are monoclinic, space group P2(1)/c, with four complex molecules in the unit cell of dimensions: a = 14.655(13), b = 8.298(10), c = 20.644(28) angstrom, beta = 108.97(9)-degrees.
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收藏
页码：25 / 30
页数：6
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