(2R,3R)-1,4-Dioxaspiro[4.4]nonane-2,3-dicarboxylic and (2R, 3R)-1,4-dioxaspiro[4.5]decane-2,3-dicarboxylic acids

被引：0
|
作者：
Minyaev, Mikhail E. [1 ]
Roitershtein, Dmitrii M. [1 ,2 ]
Vinogradov, Alexey A. [1 ]
Ananyev, Ivan V. [3 ]
Nifant'ev, Ilya E. [1 ,4 ]
机构：
[1] Russian Acad Sci, AV Topchiev Inst Petrochem Synth, 29 Leninsky Prospect, Moscow 119991, Russia
[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prospect, Moscow 119991, Russia
[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilova Str, Moscow 119991, Russia
[4] Moscow MV Lomonosov State Univ, Dept Chem, 1 Leninskie Gory Str,Bldg 3, Moscow 119991, Russia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2018年 / 74卷
关键词：
tartric acid; 1,3-dioxolane; ketals; NMR; hydrogen bonding; crystal structure;
D O I：
10.1107/S2056989018009593
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compounds, C9H12O6 and C10H14O6, were formed by careful hydrolysis of the corresponding diethyl esters. Their single crystals were grown from an ethyl acetate/hexane mixture. Crystals of both compounds have monoclinic (P2(1)) symmetry with a single molecule in the asymmetric unit. Both crystal structures are very similar and display four -CO-OH center dot center dot center dot O=C(OH)-hydrogen bonds, forming a two-dimensional double-layered framework.
引用
收藏
页码：1058 / +
页数：13
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