DISSOCIATION OF DOUBLY CHARGED SH RADICALS - AN EXPERIMENTAL AND THEORETICAL-STUDY

被引：10
|
作者：
MATHUR, D
NAGESHA, K
MARATHE, VR
机构：
[1] Tate Institute of Fundamental Research, Bombay, 400 005, Homi Bhabha Road
来源：
CHEMICAL PHYSICS LETTERS | 1992年 / 200卷 / 04期
关键词：
D O I：
10.1016/0009-2614(92)87010-M
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ion translational energy spectrometry has been applied to study unimolecular and collision-induced dissociation of dications of the SH radical. Experimentally determined values of the kinetic energy released upon dissociation are satisfactorily correlated with results of high-level ab initio calculations of potential energy curves of the ground and low-lying excited electronic states of SH2+ ions. Quantum-chemical methods in which configuration interaction effects are accounted for via the coupled-cluster approach are employed.
引用
收藏
页码：394 / 398
页数：5
相关论文
共 50 条
  • [41] THEORETICAL-STUDY OF DOUBLY CHARGED NEGATIVE-IONS OF ELEMENTAL CLUSTERS - STABILITY OF C-8(2-)
    ADAMOWICZ, L
    JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (11): : 8669 - 8670
  • [42] Existence of doubly charged lead monohydrate: Experimental evidence and theoretical examination
    Shi, TJ
    Orlova, G
    Guo, JZ
    Bohme, DK
    Hopkinson, AC
    Siu, KWM
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (25) : 7975 - 7980
  • [43] Existence of doubly charged lead monohydrate: Experimental evidence and theoretical examination
    Siu, K.W.M. (kwmsiu@yorku.ca), 1600, American Chemical Society (126):
  • [44] THEORETICAL AND EXPERIMENTAL STUDIES OF THE DOUBLY CHARGED ION HCL2+
    FOURNIER, PG
    MOUSSELMAL, M
    PEYERIMHOFF, SD
    BANICHEVICH, A
    ADAM, MY
    MORGAN, TJ
    PHYSICAL REVIEW A, 1987, 36 (06): : 2594 - 2602
  • [45] A THEORETICAL-STUDY OF THE ABSTRACTION REACTIONS OF HYDROXYL RADICALS WITH HALOGENATED ALDEHYDES
    RAYEZ, MT
    SCOLLARD, DJ
    TREACY, JJ
    SIDEBOTTOM, HW
    BALESTRAGARCIA, C
    TETON, S
    LEBRAS, G
    CHEMICAL PHYSICS LETTERS, 1994, 223 (5-6) : 452 - 458
  • [46] A THEORETICAL-STUDY OF ALPHA-SUBSTITUTED CYCLOPROPYL AND ISOPROPYL RADICALS
    LIEN, MH
    HOPKINSON, AC
    JOURNAL OF COMPUTATIONAL CHEMISTRY, 1985, 6 (04) : 274 - 281
  • [47] THEORETICAL-STUDY OF THE VIBRATIONAL FREQUENCIES OF FLUORINATED METHYL AND ETHYL RADICALS
    PADDONROW, MN
    WONG, SS
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1987, 35 (1-2): : 109 - 120
  • [48] THEORETICAL-STUDY OF THE DISSOCIATION OF A SINGLE CARBONYL FROM CHROMIUM HEXACARBONYL
    SHERWOOD, DE
    HALL, MB
    INORGANIC CHEMISTRY, 1983, 22 (01) : 93 - 100
  • [49] COULOMB BARRIERS IN THE DISSOCIATION OF DOUBLY CHARGED CLUSTERS
    GARCIAS, F
    ALONSO, JA
    LOPEZ, JM
    BARRANCO, M
    PHYSICAL REVIEW B, 1991, 43 (12): : 9459 - 9466
  • [50] Theoretical study of the Coulombic explosion in doubly charged Xe clusters
    Athanasopoulos, DC
    Schmidt, KE
    JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (23): : 9894 - 9898
12345