Bis(1-ethyl-4,4'-bipyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-kappa S-2,S')-nickelate(II)

被引：0
|
作者：
Chen, Yao [1 ]
Ning, Wei-Hua [1 ]
Liu, Jian-Lan [1 ]
机构：
[1] Nanjing Univ Technol, Coll Sci, Dept Appl Chem, Nanjing 210009, Jiangsu, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
data-to-parameter ratio = 18.7; meanω(C - C) = 0.006 A °; Rfactor = 0.051; single-crystal X-ray study; T = 296 K; wRfactor = 0.128;
D O I：
10.1107/S1600536813015493
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the anion of the title compound, (C12H13N2)[ Ni(C4N2S2)(2)], the Ni II atom is coordinated by four S atoms from two 1,2dicyanoethene- 1,2-dithiolate (mnt) ligands in a suqare-planar geometry. Weak C-H center dot center dot center dot N and C-H center dot center dot center dot S hydrogen bonds between the 1-ethyl-4,40-bipyridin-1-ium cations and mnt anions and weak pi-pi interactions between the pyridine rings of the cations [centroid-centroid distances = 3.808 (3) and 3.972 (3) angstrom] lead to a two-dimensional network parallel to (010).
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页码：M428 / +
页数：10
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