SYNTHESIS OF PHOSPHORUS-CONTAINING CARBOXYLIC-ACIDS BASED ON BIS(TRIMETHYLSILYL)HYPOPHOSPHITE

被引：2
|
作者：
BONDARENKO, NA
RAYTARSKAYA, MV
RUDOMINO, MV
TSVETKOV, EN
机构：
[1] RUSSIAN ACAD SCI,INST PHYSIOLOGICALLY ACTIVE SUBST,CHERNOGOLOVKA 142432,RUSSIA
[2] MOSCOW INST CHEM REAGENTS & HIGH PURE CHEM SUBST,MOSCOW 107258,RUSSIA
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1991年 / 56卷 / 1-4期
关键词：
BIS(HYDROXYCARBONYLMETHYL)PHOSPHINIC ACID; BIS(TRIMETHYLSILYL)HYPOPHOSPHITE; ALKYLATION; O-TRIMETHYLSILYLBIS(METHOXYCARBONYLMETHYL)PHOSPHINATE; O; O-BIS(TRIMETHYLSILYL)METHOXYCARBONYLMETHYL-PHOSPHONITE; METHANOLYSIS; HYDROLYSIS;
D O I：
10.1080/10426509108038081
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Silylation of ammonium hypophosphite (1) with hexamethyldisilasane (HMDS) followed by alkylation of the intermediate bis(trimethylsilyl)hypophosphite (2) with methylchloroacetate in the presence of HMDS gives O-trimethylsilylbis(methoxycarbonylmethyl)phosphinate (3) and O, Obis(trimethylsilyl)-methoxycarbonylmethylphosphonite (4). Methanolysis of phosphinate 3 gives bis(methoxycarbonyl-methyl)phosphinic acid (5), the hydrolysis of which leads to bis(hydroxycarbonylmethyl)phosphinic acid (6). Treatment of the acids 5 and 6 with sodium hydroxide gives trisodium salt (7). © 1991, Taylor & Francis Group, LLC. All rights reserved.
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页码：179 / 182
页数：4
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