DIISOPROPYLAMINOMETHYLIDYNE COMPLEXES OF IRON, CHROMIUM, MOLYBDENUM AND TUNGSTEN

被引：18
|
作者：
ANDERSON, S [1 ]
HILL, AF [1 ]
机构：
[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 394卷 / 1-3期
关键词：
D O I：
10.1016/0022-328X(90)87274-H
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of [M(CO)n] (n = 6, M = Cr, Mo, W; n = 5, M = Fe) successively with LiNiPr2, (CF3CO)2O, and PPh3 leads to the thermally stable diisopropylaminomethylidyne complexes [M(CNiPr2)(O2CCF3)(CO)3(PPh3)] (M = Cr, Mo, W) and [Fe(CNiPr2)(O2CCF3)(CO)2(PPh3)] in high yield. The latter is the first neutral mononuclear carbyne complex of iron. © 1990.
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页码：C24 / C26
页数：3
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