COMPLEXES WITH MACROCYCLIC LIGANDS .2. SYNTHESIS, STRUCTURE AND ELECTROCHEMICAL PROPERTIES OF A MACROCYCLIC CU2(II)MN(II) COMPLEX OF SCHIFF-BASE TYPE

被引：13
|
作者：
BRYCHCY, K
JENS, KJ
TILSET, M
BEHRENS, U
机构：
[1] UNIV HAMBURG, INST ANORGAN & ANGEW CHEM, MARTIN LUTHER KING PL 6, D-20146 HAMBURG, GERMANY
[2] STATOIL, N-3960 STATHELLE, NORWAY
[3] UNIV OSLO, DEPT CHEM, N-0315 OSLO 3, NORWAY
来源：
CHEMISCHE BERICHTE-RECUEIL | 1994年 / 127卷 / 06期
关键词：
COPPER(II) COMPLEXES; MANGAN(II); COMPLEXES; TRINUCLEAR; SCHIFF BASES; MACROCYCLIC; REDOX PROPERTIES;
D O I：
10.1002/cber.19941270605
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel trinuclear Cu2Mn complex 4 of a macrocyclic Schiff base ligand obtained by condensation of 5-tert-butyl-2-hydroxy-1,3-benzenedicarbaldehyde with 1,2-phenylenediamine was synthesized. The molecular structure of 4 was determined by X-ray diffraction revealing a sandwich-type structure as depicted by Figure 2. Electrochemical investigations (DCV measurements) showed two one-electron reduction steps for the copper ions at E1/2 = -1.383 and -1.652 V (vs. Cp2Fe/Cp2Fe)+.
引用
收藏
页码：991 / 995
页数：5
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