ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE BY THE USE OF COPPER TUBE ELECTRODE

被引:8
|
作者
OHTA, K
HASIMOTO, A
MIZUNO, T
机构
[1] Department of Chemistry for Materials, Faculty of Engineering, Mie University, Tsu, Mie
关键词
D O I
10.1016/0196-8904(95)00083-P
中图分类号
O414.1 [热力学];
学科分类号
摘要
A copper tube used as electrode was evaluated for the electrochemical reduction of carbon dioxide under atmospheric pressure. The applied electric potential was -1.4 to -2.0 V. The main products from carbon dioxide were methylalcohol and formic acid. Under the optimum experimental conditions, the Faradaic efficiencies for methylalcohol, formic acid and methane from carbon dioxide in the electrochemical reduction system were 18 % at -1.7 V and 40 degrees C, 0.91 % at -1.8 V and 20 degrees C, and 0.013 % at -1.8 v and 20 degrees C, respectively.
引用
收藏
页码:625 / 628
页数:4
相关论文
共 50 条
  • [31] ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE ON CONDUCTIVE METALLIC OXIDES
    BANDI, A
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (07) : 2157 - 2160
  • [32] ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE IN LOW PROTON MEDIA
    GRESSIN, JC
    MICHELET, D
    NADJO, L
    SAVEANT, JM
    [J]. NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1979, 3 (8-9): : 545 - 554
  • [33] ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE MEDIATED BY MOLECULAR CATALYSTS
    COLLIN, JP
    SAUVAGE, JP
    [J]. COORDINATION CHEMISTRY REVIEWS, 1989, 93 (02) : 245 - 268
  • [34] Electrochemical Reduction of Carbon Dioxide to Formate on Palladium-Copper Alloy Nanoparticulate Electrode
    Takashima, Toshihiro
    Suzuki, Tomohiro
    Irie, Hiroshi
    [J]. ELECTROCHEMISTRY, 2019, 87 (02) : 134 - 138
  • [35] Selective electrochemical reduction of carbon dioxide to ethylene on a copper hydroxide nitrate nanostructure electrode
    Wang, Mang
    Zhang, Qixing
    Xie, Qixian
    Wan, Lili
    Zhao, Ying
    Zhang, Xiaodan
    Luo, Jingshan
    [J]. NANOSCALE, 2020, 12 (32) : 17013 - 17019
  • [36] EFFECT OF CADMIUM DEPOSITION ON ELECTROREDUCTION OF CARBON-DIOXIDE BY A COPPER ELECTRODE
    KOGA, O
    MURATA, A
    HORI, Y
    [J]. NIPPON KAGAKU KAISHI, 1991, (06) : 873 - 878
  • [37] Electrochemical reduction of carbon dioxide on copper electrode in a carbon dioxide methanol mixture under near-critical conditions
    Mazin, VM
    Mysov, EI
    Grinberg, VA
    [J]. RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 1997, 33 (07) : 779 - 780
  • [38] CARBON-DIOXIDE REDUCTION
    TAYLOR, DAH
    [J]. NATURE, 1976, 260 (5546) : 8 - 8
  • [39] REDUCTION OF CARBON-DIOXIDE
    AURIANBLAJENI, B
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 172 - COLL
  • [40] ELECTRODE REDUCTION KINETICS OF CARBON-DIOXIDE IN AQUEOUS-SOLUTION
    RYU, J
    ANDERSEN, TN
    EYRING, H
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1972, 76 (22): : 3278 - &