RHODIUM(I) COMPLEXES WITH 1,5-DIAZABICYCLO[4.3.0]NON-5-ENE (DBN) AS A LIGAND - [RHCL(NBD)] (I) AND [RH(DBN)2(COD)][PF6] (II) (NBD = NORBORNADIENE, COD = 1,5-CYCLOOCTADIENE)

被引：3

作者：

FLORKE, U

HAUPT, HJ

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194003823

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Both of the complexes studied, (eta4-bicyclo[2.2.1]hepta-2,5-diene)chloro(1,5-diazabicyolo[4.3.0]non-5-ene-N5)-rhodium(I), [RhCl(C7H8)(C7H12N2)], (1), and (eta4-1,5-cyclooctadiene)bis(1,5-diazabicyclo[4.3.0]non-5-ene-N5)rhodium hexafluorophosphate, [Rh(C7H12N2)-(C8H12)][PF6], (II), show planar quadratically coordinated Rh atoms with dbn as and N-donor ligand. Two different conformations of the dbn ligand are present in each complex. The Rh-ligand bond distances and angles depend on the different N, Cl and diene coordination of the metal atoms.

引用

页码：1424 / 1427

页数：4

共 40 条

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[28] PREPARATION AND STRUCTURE OF [RH(ETA-5-C5H4(2-C5H4N))(ETA-5-C5H4PPH2))(COD)]PF6 AND [IR(H)(FE[ETA-5-C5H3(2-C5H4N)](ETA-5-C5H4PPH2))(COD)]PF6 - A RH(1) COMPLEX HAVING A C-H ... RH(1) INTERACTION AND A HYDRIDO IR(III) COMPLEX (WHERE COD = CYCLO-OCTA-1,5-DIENE)
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